ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
Question
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Chapter 7.3, Problem 3PTS

(a)

Interpretation Introduction

Interpretation:

The product of SN2 reaction of (S)-2-chloropentane and NaSH is to be interpreted.

Concept introduction:

In the SN2 reaction mechanism, two reactants take part in the rate determining step. The rate-determining step is the step of a multistep reaction that determines the order of the reaction. The reaction occurs with the formation of the transition state. The transition state further converts to the product.

(b)

Interpretation Introduction

Interpretation:

The product of SN2 reaction of (R)-3-iodohexane and NaCl is to be interpreted.

Concept introduction:

In the SN2 reaction mechanism, two reactants take part in the rate determining step. The rate determining step is the step of a multistep reaction which determines the order of reaction. The reaction occurs with the formation of transition state. The transition state further converts to the product.

(c)

Interpretation Introduction

Interpretation:

The product of SN2 reaction of (R)-2-bromohexane and NaCN is to be interpreted.

Concept introduction:

In the SN2 reaction mechanism, two reactants take part in the rate determining step. The rate determining step is the step of a multistep reaction which determines the order of reaction. The reaction occurs with the formation of transition state. The transition state further converts to the product.

(d)

Interpretation Introduction

Interpretation:

The product of SN2 reaction of 1-bromoheptane and NaOH is to be interpreted.

Concept introduction:

In the SN2 reaction mechanism, two reactants take part in the rate determining step. The rate determining step is the step of a multistep reaction which determines the order of reaction. The reaction occurs with the formation of transition state. The transition state further converts to the product.

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Draw the substitution products for each of the following reactions; if the products can exist as stereoisomers, show what stereoisomers are obtained: a. (R)-2-bromopentane + CH3O-           b. (R)-3-bromo-3-methylheptane + CH3OH c. benzyl chloride + CH3CH2OH  d. allyl chloride + CH3OH e. 1-bromo-2-butene + CH3O- f. 1-bromo-2-butene + CH3OH
draw the major product of the following reactions

Chapter 7 Solutions

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS

Ch. 7.5 - Prob. 9CCCh. 7.6 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Prob. 12PTSCh. 7.7 - Prob. 13PTSCh. 7.7 - Prob. 14ATSCh. 7.7 - Prob. 4LTSCh. 7.7 - Prob. 16ATSCh. 7.7 - Prob. 17CCCh. 7.7 - Prob. 18CCCh. 7.7 - Prob. 5LTSCh. 7.7 - Prob. 19PTSCh. 7.7 - Prob. 20ATSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 22ATSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 25CCCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.9 - Prob. 7LTSCh. 7.9 - Prob. 29ATSCh. 7.9 - Prob. 30ATSCh. 7.9 - Prob. 31ATSCh. 7.10 - Prob. 32CCCh. 7.10 - Prob. 33CCCh. 7.10 - Prob. 34CCCh. 7.11 - Prob. 8LTSCh. 7.11 - Prob. 35PTSCh. 7.11 - Prob. 36PTSCh. 7.11 - Prob. 37ATSCh. 7.11 - Prob. 9LTSCh. 7.11 - Prob. 40PTSCh. 7.11 - Prob. 41ATSCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.12 - Prob. 44CCCh. 7.12 - Prob. 45CCCh. 7.12 - Prob. 46CCCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 64PPCh. 7 - Indicate whether you would use NaOEt or tBuOK to...Ch. 7 - Prob. 68PPCh. 7 - Draw a plausible mechanism for each of the...Ch. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Prob. 73PPCh. 7 - Prob. 74PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 81ASPCh. 7 - Prob. 87ASPCh. 7 - Prob. 90ASPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 93IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - Prob. 99IPCh. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102IPCh. 7 - Prob. 103IPCh. 7 - Prob. 105IPCh. 7 - Prob. 106IPCh. 7 - Prob. 107IPCh. 7 - Prob. 109IPCh. 7 - Prob. 110CPCh. 7 - Prob. 112CPCh. 7 - Prob. 114CP
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