ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 7, Problem 90ASP
Interpretation Introduction
Interpretation :
It is required to choose which of the provided processes is not a logical retrosynthesis.
Concept Introduction :
A Retrosynthetic analysis helps to disconnect bonds to get suitable starting materials for the synthesis of target molecule.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
In this lab you are performing your first organic synthesis and safety information on all the materials you are using must be obtained.
Companies are required to provide material safety data sheets (MSDS) for chemical compounds they sell.
Please examine the MSDS for acetic anhydride, available here. You will find GHS pictograms within the sheet that summarize the
main hazards of this compound. The pictograms are essentially the same as the symbols on WHMIS labels, available here for
reference.
Based on the pictograms, whatare the main hazards for acetic anhydride? Select as many answers as appropriate
Select one or more:
Carcinogen
Gas under pressure
Acute oral or inhalation toxicity
Corrosive
Flammable material
Oxidizing material
Self-reactive substance
In this lab you are performing your first organic synthesis and safety information on all the materials you
are using must be obtained.
Companies are required to provide material safety data sheets (MSDS) for chemical compounds they
sell.
Please examine the MSDS for acetic anhydride, available here. You will find GHS pictograms within the
sheet that summarize the main hazards of this compound. The pictograms are essentially the same as
the symbols on WHMIS labels, available here for reference.
Based on the pictograms, whatare the main hazards for acetic anhydride? Select as many answers as
appropriate however points will be deducted for incorrect guesses.
Select one or more:
Corrosive
Flammable material
Acute oral or inhalation toxicity
Oxidizing material
Carcinogen
Self-reactive substance
Gas under pressure
The nature of the primary solvent exclusively influences the miscibility of certain compounds. Toallow the incorporation of lipophilic substances, one must consider using solvents such as propanoland ethyl acetate.
A - If the first statement is TRUE and the second statement is FALSEB - If the first statement is FALSE and the second statement is TRUEC - If both statements are TRUED - If both statements are FALSE
Chapter 7 Solutions
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
Ch. 7.2 - Prob. 1CCCh. 7.3 - Prob. 2CCCh. 7.3 - Prob. 1LTSCh. 7.3 - Prob. 3PTSCh. 7.3 - Prob. 4ATSCh. 7.3 - Prob. 2LTSCh. 7.3 - Prob. 5PTSCh. 7.3 - Prob. 6ATSCh. 7.3 - Prob. 7CCCh. 7.4 - Prob. 8CC
Ch. 7.5 - Prob. 9CCCh. 7.6 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Prob. 12PTSCh. 7.7 - Prob. 13PTSCh. 7.7 - Prob. 14ATSCh. 7.7 - Prob. 4LTSCh. 7.7 - Prob. 16ATSCh. 7.7 - Prob. 17CCCh. 7.7 - Prob. 18CCCh. 7.7 - Prob. 5LTSCh. 7.7 - Prob. 19PTSCh. 7.7 - Prob. 20ATSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 22ATSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 25CCCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.9 - Prob. 7LTSCh. 7.9 - Prob. 29ATSCh. 7.9 - Prob. 30ATSCh. 7.9 - Prob. 31ATSCh. 7.10 - Prob. 32CCCh. 7.10 - Prob. 33CCCh. 7.10 - Prob. 34CCCh. 7.11 - Prob. 8LTSCh. 7.11 - Prob. 35PTSCh. 7.11 - Prob. 36PTSCh. 7.11 - Prob. 37ATSCh. 7.11 - Prob. 9LTSCh. 7.11 - Prob. 40PTSCh. 7.11 - Prob. 41ATSCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.12 - Prob. 44CCCh. 7.12 - Prob. 45CCCh. 7.12 - Prob. 46CCCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 64PPCh. 7 - Indicate whether you would use NaOEt or tBuOK to...Ch. 7 - Prob. 68PPCh. 7 - Draw a plausible mechanism for each of the...Ch. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Prob. 73PPCh. 7 - Prob. 74PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 81ASPCh. 7 - Prob. 87ASPCh. 7 - Prob. 90ASPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 93IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - Prob. 99IPCh. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102IPCh. 7 - Prob. 103IPCh. 7 - Prob. 105IPCh. 7 - Prob. 106IPCh. 7 - Prob. 107IPCh. 7 - Prob. 109IPCh. 7 - Prob. 110CPCh. 7 - Prob. 112CPCh. 7 - Prob. 114CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 20:32 hydroxide 2. Using curved arrows, show the deprotonation mechanism of phenol with (OH). Also, provide the structure of the product of this deprotonation. Start answering this question by drawing the structure of phenol. Then hydroxide ion. Find your most reactive electrons and draw the curved arrow that shows where they would go to deprotonate phenol. Then "make a bond break a bond" write they question 3. Provide valid resonance structures for the product of the previous arrow(s) charge moving onto the ortho- and para positions. Use curved to show how the charge resonates to the next structure in your scheme. all the proper notations for depicting resonance. that show the in the structures Be sure to use Send a chat Carrow_forwardAlcohols are very useful organic compounds because there are many ways to synthesize larger and more complex molecules starting with simple alcohols. The reactions you will examine form a strong basis for synthetic tools that an organic chemist would use. You will be expected to predict the major products of reactions under the conditions given. The key to doing this is to look carefully at the conditions and remember how those conditions affect the products. It is a good idea to have an index card file of the reactions as you learn them. Dehydration (loss of water) - There are two forms of dehydration reactions with alcohols - ether formation and elimination (alkene formation). In both reactions you are looking for the components of water (OH and H) that will be removed in the reaction. Ether Formation - Two alcohols will form an ether link by loss of water forming an ether product with an acidic catalyst (typically H2SO4) at 140\deg C. One alcohol loses the hydroxyl group and one…arrow_forwardFirst, draw your chosen compounds including any non-bonding electrons and non-zero formal charges Circle and name any pH-sensitive functional groups. Choose an organic solvent that will dissolve both or your compounds and an aqueous solution (i.e. conc. aqueous NaOH, 5% aq. NaHCO3, or 3M HCl) that would successfully separate the two compounds selected.arrow_forward
- Hydroxide acts as a nucleophile in protein degradation by hydrolysis of the peptide bond in water. Draw out an arrow pushing mechanism of the hydrolysis of a peptide bond. Identify the nucleophile and the electrophile in this reaction.arrow_forwardAlcohols are acidic in nature. Therefore, a strong base can abstract the acidic hydrogen atom of the alcohol in a process known as deprotonation. The alcohol forms an alkoxide ion by losing the proton attached to the oxygen atom of the hydroxyl ( -OH) group. The alkoxide formed can act as a base or a nucleophile depending on the substrate and reaction conditions. However, not all bases can abstract the acidic proton of alcohols and not all alcohols easily lose the proton. Deprotonation depends on the strength of the base and the acidity of the alcohol. Strong bases, such as NaNH2, can easily abstract a proton from almost all alcohols. Likewise, more acidic alcohols lose a proton more easily. Determine which of the following reactions would undergo deprotonation based on the strength of the base and the acidity of the alcohol. Check all that apply. ► View Available Hint(s) CH3CH,OH + NH3 →CH,CH,O-NH CH3 CH3 H3C-C-H+NH3 → H3 C-C-H OH O-NH CH3CH2OH + NaNH, → CH3CH,O-Na* + NH3 CHC12 Cl₂…arrow_forward55(a-d)arrow_forward
- ciple Attempts Not allowed. This test can only be taken once. ce Completion Once started, this test must be completed in one sitting. Do not leave the test before clicking Save and Submit This test does not allow backtracking. Changes to the answer after submission are prohibited. emaining Time: 52 minutes, 44 seconds. Question Completion Status: A Moving to the next question prevents changes to this answer. Question 2 Reaction of arenediazonium salts with aryl benzene give.... o Aryl halied Benzonitrile Phenole Azo dayes A Moving to the next question prevents changes to this answer. P Type here to search 1HUAWE F1 F2 F3 F4 F5 F6 F7 %23 24 % & 2 5 6. 7 8. Q W E T Y. us A H. 1S C, Z C VI B U DIarrow_forwardANSWER ALL AND WILL GIVE YOU THUMBS UP AND RATE YOU GOOD Classify the following examples to the given agents. CHOICES: Suspending agent Emulsifying agent QUESTIONS: Bentonite Kaolin Lecithin Carbomer Polysorbate 20 Carrageenan Methyl cellulose Ceteareth 20 Tragacanth Mustardarrow_forwardH NH₂ ཡིནྣཾ ༥ ཨ ཨནྡྷ༥ ༠ ཨི་ཝཱ, ཙ ཨ་ར༩ H NH3+ the acidity of the amine ion drives the reaction to shift toward the conjugate base of the carboxylic acid product. the resulting carboxylic acid ion is a weaker base than an acetate ion. O aldehydes are more reactive toward nucleophiles than ketones. Onucleophilic attack occurs preferentially at the less hindered carbon of the formyl group.arrow_forward
- < Question 28 of 85 Submit 1. LiN¹-Pr₂/THF 2. CH3CH2Br CH3 A) This reaction would require a different solvent. B) The base is too weak to deprotonate this compound. C) There is a problem with the order of addition. D) The wrong nucleophilic position was used. Tap here or pull up for additional resourcesarrow_forward3. You are given a mixture of aspirin, phenol, and naphthalene that you need to separate. i) Draw the structures of each, and identify if they are acidic, basic, or neutral compounds. For each compound draw their reaction with the appropriate acidic or basic conditions that will change their solubility and allow them to be separated. ii) What modifications would you have to make to the experimental protocol in order to separate these three compounds? Provide specifics.arrow_forwardThe conjugate base of diethyl malonate can serve as a nucleophile to attack a wide range of electrophiles. Identify the product that is formed when the conjugate base of diethyl malonate reacts with the following electrophile followed by acid workup when relevant: Modify the provided structures of diethyl malonate and the given electrophile to draw the product formed. Note: the eraser tool can be used to erase bonds, and atoms can be moved by selecting them with the selector tool and then dragging the selected atom(s) to a new position. If you make a mistake, you can use Ctrl-Z or the Undo tool. бль EtO OEt Edit Drawingarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning