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Chapter 8 Solutions
Chemistry by OpenStax (2015-05-04)
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CHEMISTRY-TEXT
Chemistry: Structure and Properties
- Consider the polyatomic ion IO65-. How many pairs of electrons are around the central iodine atom? What is its hybridization? Describe the geometry of the ion.arrow_forwardIn addition to NF3, two other fluoro derivatives of nitrogen are known: N2F4 and N2F2. What shapes do you predict for these two molecules? What is the hybridization for the nitrogen in each molecule?arrow_forwardAspirin, or acetylsalicylic acid, has the formula C9H8O4 and the skeleton structure (a) Complete the Lewis structure and give the number of bonds and bonds in aspirin. (b) What is the hybridization about the CO2H carbon atom (colored blue)? (c) What is the hybridization about the carbon atom in the benzene-like ring that is bonded to an oxygen atom (colored red)? Also, what is the hybridization of the oxygen atom bonded to this carbon atom?arrow_forward
- Acrylonitrile, C3H3N is the building mer Orlon. Its Lewis structure is What is the hybridization of nitrogen and of the three numbered carbon atoms?arrow_forwardDraw the Lewis structure for 1, 1-dimethylhydrazine [(CH3)2NNH2, a compound used as a rocket fuel]. What: is the hybridization for the two nitrogen atoms in this molecule? What orbitals overlap to form the bond between the nitrogen atoms?arrow_forwardMethylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) How many sigma bonds are in the molecule? (b) How many pi bonds are in the molecule? (c) What is the hybridization of the carbon atom bonded to nitrogen? (d) What is the hybridization of the carbon atom bonded to oxygen? (e) What is the hybridization of the double-bonded oxygen?arrow_forward
- The sulfamate ion, H2NSO3, can be thought of as having been formed from the amide ion, NH2, and sulphur trioxide, SO3. (a) What are the electron-pair and molecular geometries or the amide ion and or SO3? What are the hybridizations of the N and S atoms, respectively? (b) Sketch a structure for the sulfamate ion, and estimate the bond angles. (c) What changes in hybridization do you expect for N and S in the course of the reaction NH2 + SO3 H2NSO3? (d) Is SO3 the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion? Does the electrostatic potential map shown below confirm your prediction?arrow_forwardGamma hydroxybutyric acid, GHB, infamous as a date rape drug, is used illicitly because of its effects on the nervous system. The condensed molecular formula for GHB is HO(CH2)3COOH. (a) Write the Lewis structure for GHB. (b) Identify the hybridization of the carbon atom in the CH2 groups and of the terminal carbon. (c) Is hydrogen bonding possible in GHB? If so, write Lewis structures to illustrate the hydrogen bonding. (d) Which carbon atoms are involved in sigma bonds? In pi bonds? (e) Which oxygen atom is involved in sigma bonds? In pi bonds?arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning