Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with Quick Prep and Student Solutions Manual 24-Months Printed Access Card
3rd Edition
ISBN: 9781305600874
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 8, Problem 8.14PAE
Interpretation Introduction
Interpretation: hcp and ccp structures have same coordination number has to be explained.
Concept introduction:
- hcp is hexagonal close packed structure in which the stacking sequence follows ABABAB.
- fcc is face centered cubic structure in which the stacking sequence follows ABCABCABC.
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3. On the basis of ionic charge and ionic radii given in Table 1, predict crystal structures for the
following materials: (
a. CaO (b) MnS (c) KBr (d) CsBr
b. Justify your selections.
Table 1: Ionic Radii for Several Cations and Anions
Ionic
Radius (am)
Ionic
Cation
Radius (nm)
Anion
0.053
Br
0.196
Ba?+
Ca?+
0.136
0.181
0.100
F
0.133
Cs*
0.170
0.220
Fe2+
0.077
0.140
Fe
0.069
0.184
K*
0.138
Mg
Mn2*
0.072
0.067
Na*
0.102
Ni+
0.069
Sit+
0.040
0.061
Explain the term crystal radii?
4. Briefly explain why chemically similar alkali metal chlorides, NaCl and CsCl, have different crystalline structures, while MnS and NaCl pack in the same crystalline structure.
Chapter 8 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with Quick Prep and Student Solutions Manual 24-Months Printed Access Card
Ch. 8 - Prob. 1COCh. 8 - • describe the arrangement of atoms in the common...Ch. 8 - • use bind theory to describe bonding in solids.Ch. 8 - Prob. 4COCh. 8 - Prob. 5COCh. 8 - Prob. 6COCh. 8 - Prob. 7COCh. 8 - • explain the connection between intermolecular...Ch. 8 - Prob. 9COCh. 8 - Prob. 10CO
Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Using circles, draw regular two-dimensional...Ch. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - Prob. 8.13PAECh. 8 - Prob. 8.14PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.16PAECh. 8 - Prob. 8.17PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.21PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.23PAECh. 8 - Prob. 8.24PAECh. 8 - Prob. 8.25PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Prob. 8.34PAECh. 8 - Prob. 8.35PAECh. 8 - Prob. 8.36PAECh. 8 - Prob. 8.37PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - Prob. 8.43PAECh. 8 - Prob. 8.44PAECh. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.48PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.50PAECh. 8 - Prob. 8.51PAECh. 8 - Explain from a molecular perspective why graphite...Ch. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Suppose that three unknown pure substances are...Ch. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - Prob. 8.66PAECh. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Why is there no isotactic or syndiotactic form of...Ch. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.74PAECh. 8 - Prob. 8.75PAECh. 8 - Prob. 8.76PAECh. 8 - Prob. 8.77PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.79PAECh. 8 - Prob. 8.80PAECh. 8 - Prob. 8.81PAECh. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 In previous chapters, we have noted that...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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