(a)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process.
(b)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
(c)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
(d)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
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Chapter 8 Solutions
Organic Chemistry (9th Edition)
- a) Write down the products that will occur when you extract HBr from 2-bromo-3-methyl butane in a basic medium, State the reaction conditions. Show which product is the main product. b) Does the main product show the geometric isomer, so please write together. If it shows write the isomers. c) Write the product that will be formed when the main product reacts with KMnO4 in a basic environment in coldarrow_forwardwrite the reaction of the action of methyl-2, bromo-2-propane with hot KOH solution. a) Name the formed product b) Explain why the reaction takes place according to the SNI mechanismarrow_forwarda) Write down the products that will occur when you withdraw HBr from 2-bromine-3-methyl butane in a basic medium, State the reaction conditions. Show which product is the main product. b) Does the main product show the geometric isomer, so please write together. If it shows write the isomers. c) Write the product that will be formed when the main product reacts with KMnO4 in a basic environment in cold.arrow_forward
- Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?arrow_forwardWhat are the final products for these reactions? *mechanisms not necessaryarrow_forwardOrganotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides.One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4Al(C2H5)3 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.230 L of SnCl4 (d = 2.226 g/mL) was treated with 0.396 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). If 0.335 L of tetraethylstannane (d = 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?arrow_forward
- Which of the following reagent/s will efficiently convert isopropylbenzene to 2- and 4-chloro-1-isopropylbenzene? Select one: a. HCl in the presence of peroxides b. SOCl2 c. PCl3 d. Cl2, FeCl3 e. Cl2, initiated by heat or lightarrow_forwardPredict the products, including stereochemistry where appropriate, for the m-chloroperoxybenzoic acid epoxidations of the following alkenes.(a) cis-hex-2-ene (b) trans-hex-2-ene(c) cis-cyclodecene (d) trans-cyclodecenearrow_forwardThe structure below represents a tetrahedral alkoxide-ion intermediate formed by addition of a nucleophile to a carboxylic acid derivative. Draw both the starting acid derivative and the ultimate carboxylic acid derivative product. Do not include the product formed by the leaving group.arrow_forward
- (a) How will you carry out the following conversions?(i) Acetylene to Acetic acid (ii) Toluene to m-nitrobenzoic acid(iii) Ethanol to Acetone(b) Give reasons :(i) Chloroacetic acid is stronger than acetic acid.(ii) pH of reaction should be carefully controlled while preparing ammonia derivatives of carbonyl compounds.arrow_forwardPredict the product of this reaction -7-Bromo-3-octene + Cl2 -1-Cyclohexene + H2 -2,5-dichlorohept-3-ene + H2 --->arrow_forwardWhich of the following are intermediates in the reaction of excess methylmagnesium bromide with ethyl benzoate (shown in Image18) to make 2-phenyl-2-propanol? A. I and II B. I and III C. II and III D. I, II, and III (they are all intermediates)arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning