Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 9, Problem 9.13P

(a)

Interpretation Introduction

Interpretation:

The resonance integral β for the series consisting of ethane, butadiene, hexatriene and octatetraene has to be estimated.

Concept Introduction:

E=hcλ

Where,

    h=6.626×1034Jsm=9.1×1031kg

En is the energy of nth orbital.

n is the principal quantum number.

L is the length of the box.

(b)

Interpretation Introduction

Interpretation:

The pi electron delocalization energy of octatetraene has to be calculated.

Concept Introduction:

E=hcλ

Where,

    h=6.626×1034Jsm=9.1×1031kg

En is the energy of nth orbital.

n is the principal quantum number.

L is the length of the box.

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