Concept explainers
(a)
Interpretation:
The overlap between an
Concept Introduction:
The overlap of atomic orbital of one atom with the atomic orbital of another atom is called the overlap integral.
The overlap integral between H1s orbital and H2p orbital on nuclei can be written as
(b)
Interpretation:
The graph of overlap versus separation between nuclei has to be plotted. Also the separation at which maximum overlap is obtained has to be mentioned.
Concept Introduction:
The overlap of atomic orbital of one atom with the atomic orbital of another atom is called the overlap integral.
The overlap integral between H1s orbital and H2p orbital on nuclei can be written as
(c)
Interpretation:
A linear combination of orbital A and B which is not overlapping with the given wave function has to be found.
Concept Introduction:
Two functions are said to be orthogonal if the integral of their product is zero.
Consider two functions X and Y. If these functions are orthogonal then
A function is said to be normalized if the integral of its product to itself is 1.
Consider a function X, if this function is normalized then
(d)
Interpretation:
The given wave function has to be normalized in terms of
Concept Introduction:
Two functions are said to be orthogonal if the integral of their product is zero.
Consider two functions X and Y. If these functions are orthogonal then
A function is said to be normalized if the integral of its product to itself is 1.
Consider a function X, if this function is normalized then
Want to see the full answer?
Check out a sample textbook solutionChapter 9 Solutions
Elements Of Physical Chemistry
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY