(a) Interpretation: The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH − is to be predicted. Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes . The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 1

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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11:43 Q1. (a) (c) (d) (b) Two stereoisomers of but-2-ene are formed when 2-bromobutane reacts with ethanolic potassium hydroxide. (i) Explain what is meant by the term stereoisomers. Library Name and outline a mechanism for the reaction of 2-bromo-2-methylpropane with ethanolic potassium hydroxide to form the alkene 2-methylpropene, (CH3)2C=CH₂ Name of mechanism Mechanism (ii) Draw the structures and give the names of the two stereoisomers of but-2-ene. Stereoisomer 1 Name (iii) Name this type of stereoisomerism. Select Name Stereoisomer 2 When 2-bromo-2-methylpropane reacts with aqueous potassium hydroxide, 2-methylpropan-2-ol is formed as shown by the following equation. CH3 H₂C-C-CH3 + KOH Br Page 2 of 14 CH3 H3C-C-CH3 + KBr ОН State the role of the hydroxide ions in this reaction. Write an equation for the reaction that occurs when CH3CH₂CH₂CH₂Br reacts with an excess of ammonia. Name the organic product of this reaction. Equation Name of product 9,284 Photos, 1,166 Videos For You…

Answer 2

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 3

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 4

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 5

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 6

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 7

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains the curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with

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