The species, O 2 + , O 2 , O 2 − , O 2 2 − are to be arranged in the increasing order of their bond length. Concept introduction: One of the most useful parameters to discuss the characteristics of bonds is the bond order. The bond order is directly related with the bond length and strength of the bond. Higher the bond order, shorter will be the bond. The bond dissociation energy determines the strength of a bond.

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Answer 1

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9C.3BE

Interpretation Introduction

Interpretation:

The species, O2+,O2,O2−,O22− are to be arranged in the increasing order of their bond length.

Concept introduction:

One of the most useful parameters to discuss the characteristics of bonds is the bond order. The bond order is directly related with the bond length and strength of the bond. Higher the bond order, shorter will be the bond. The bond dissociation energy determines the strength of a bond.

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Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9C.3BE

Interpretation Introduction

Interpretation:

The species, O2+,O2,O2−,O22− are to be arranged in the increasing order of their bond length.

Concept introduction:

One of the most useful parameters to discuss the characteristics of bonds is the bond order. The bond order is directly related with the bond length and strength of the bond. Higher the bond order, shorter will be the bond. The bond dissociation energy determines the strength of a bond.

Expert Solution & Answer

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9C.3BE

Interpretation Introduction

Interpretation:

The species, O2+,O2,O2−,O22− are to be arranged in the increasing order of their bond length.

Concept introduction:

One of the most useful parameters to discuss the characteristics of bonds is the bond order. The bond order is directly related with the bond length and strength of the bond. Higher the bond order, shorter will be the bond. The bond dissociation energy determines the strength of a bond.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9C.3BE

Interpretation Introduction