PiQ Exam 2
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Review Test Submission: Additional Practice Exam 2 with feedback ( A Remix)
2021SP-22142-CHEM1332-Fundamentals of Chemistry 2
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2021SP-22142-CHEM1332-Fundamentals of Chemistry 2
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Additional Practice Exam 2 with feedback ( A Remix)
Started
4/2/21 5:36 PM
Submitted
4/2/21 6:40 PM
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Score
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Elapsed
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Instructions
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For Ñll-in the blank questions, spelling counts, and atomic symbols must start with capital
letters.
For numerical entry problems:
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agrees within plus or minus 2% of the expected value. Therefore unless otherwise
speciÑed, you should report at least three signiÑcant Ñgures and enter your value with no
units.
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This must be
done as exponential notation, using
a capital "E"
.
For example, 1921 would be entered
as 1.921
E
3; 0.00789 would be 7.89
E
-3.
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For
example, the value 6789.123 has three decimal places.
Some questions may specify that the log-base 10 of the calculated values should be
entered as the answer with at least two decimal places.
For example, a calculated value
of
0.00789 would be entered as
log(0.00789) = -2.103.
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given:
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Submitted Answers, Correct Answers, Feedback
Question 1
Selected Answer:
Correct Answer:
Response
Feedback:
The molecular geometry of the XeF
4
molecule is ________, and this molecule is ________. square planar, nonpolar
square planar, nonpolar
(Hint: start by drawing the Lewis dot structure, use the electronegativity
difference to determine the bond polarity, and finally consider how the dipoles
(vectors) combine to determine the overall molecular polarity.)
Question 2
Selected Answer:
Correct Answer:
Response Feedback:
Consider the following reaction and its equilibrium constant: 4 CuO(s) + CH
4
(g) CO
2
(g) + 4 Cu(s) + 2 H
2
O(g) K
c
= 1.10 A reaction mixture contains 0.22 M CH
4
, 0.67 M CO
2
and 1.3 M H
2
O. Which of the following
statements is TRUE concerning this system?
The reaction will shift in the direction of reactants.
The reaction will shift in the direction of reactants.
IF
Q
> K
reverse direction
1 out of 1 points
1 out of 1 points
Q
= K
at equilibrium
Q
< K
forward direction
Question 3
Selected Answer:
2.51E0
Correct Answer:
2.51E0 ± 2%
Response
Feedback:
At a given temperature, the K
eq
for the equilibrium below is 0.399. SO
2
(g) + O
2
(g) SO
3
(g) What is the value of K
eq
at this temperature for the following reaction? SO
3
(g) SO
2
(g) + O
2
(g) If you multiply an equation by a number, you raise the equilibrium
constant to that power.
If you reverse a reaction, you take the reciprocal of the equilibrium
constant.
If you add two equations, you multiply their equilibrium constants.
Question 4
Selected Answer:
6.18E-2
Correct Answer:
6.18E-2 ± 2%
Response Feedback:
Given the following reaction at equilibrium, if K
p
= 2.45 at 210 °C, K
c
= ________. PCl
5
(g) PCl
3
(g) + Cl
2
(g)
, with R = 0.0821 atm L / (mol K) and T in K.
Question 5
Selected Answer:
3.73E-5
At a given temperature, the reaction,
H
2
(g) + I
2
(g)
2HI (g), has a value of K
eq
= 771.
If the hydrogen concentration is 0.00541 M
and the hydrogen iodide concentration is 0.01248
M, what is the molar concentration of the iodine at equilibrium? 1 out of 1 points
1 out of 1 points
1 out of 1 points
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Correct Answer:
3.73E-5 ± 2%
Response
Feedback:
The equilibrium constant is equal to the products over the reactants raised to
the stoichiometric ccoeÔcients (leaving out pure liquids and solid). Once your
write the equilibrium equation, you then substitute in the given values and
solved for the unknown concentration.
Question 6
Selected Answer:
9.352E1
Correct Answer:
9.35E1 ± 2
Response
Feedback:
Iodine and bromine react as shown below:
I
2
(g) + Br
2
(g) 2IBr (g). If 0.531 mol of I
2
and 0.531 mol of Br
2
are placed into a sealed 1.00 L Òask, and at
equilibrium the Òask contains 0.88 mol of IBr, what is the
value of the equilibrium constant,
K
eq
? (Hint: you will needed to Ñgure out the amounts of each substance at equilibrium using
stoichiometry, before you can substitute into the equilibrium expression. An ICE table can
help you organize this type of data. )
First calculate the concentrations at equilibrium using stoichiometry. They
substitute the concentrations into the equilibrium expression to Ñnd the value
of K
eq
.
Question 7
Selected Answer:
Correct Answer:
Response
Feedback:
The equilibrium constant is given for two of the reactions below. Determine the value of the
missing equilibrium constant. A(g) + 2B(g) AB
2
(g) Kc = 59 AB
2
(g) + B(g) AB
3
(g) K
c
= ? A(g) + 3B(g) AB
3
(g) K
c
= 478
8.1
8.1
If you multiply an equation by a number, you raise the equilibrium
constant to that power.
If you reverse a reaction, you take the reciprocal of the equilibrium
constant.
If you add two equations, you multiply their equilibrium constants.
1 out of 1 points
1 out of 1 points
Question 8
Selected
Answer:
Correct
Answer:
Response
Feedback:
Consider the following reaction at equilibrium. What eÖect will adding some graphite have on
the system? CO
2
(g) + C(graphite) 2 CO(g)
No eÖect will be observed since C is not included in the equilibrium
expression.
No eÖect will be observed since C is not included in the equilibrium
expression.
Because the equilibrium is heterogeneous, the solid does not appear in the
equilibrium expression and therefore adding and subtracting graphite will not
shift the equilibrium.
Question 9
Selected Answer:
Correct Answer:
Response
Feedback:
An aqueous solution of ________ will produce an acidic solution.
NH
4
NO
3
NH
4
NO
3
Conjugate bases of strong acids are neutral (i.e. not bases).
(Based on the list of seven strong acids, this mean the ions HSO
4
-
, NO
3
-
, I
-
, Br
-
,
Cl
-
, ClO
3
-
, and ClO
4
-
can form neutral salts.
Group I and II cations form neutral salts, but since ammonium is the conjugate
base of a weak acid (ammonia) it forms an acidic salt.
Anions that are conjugate bases of weak acids form basic salts.
Question 10
Selected Answer:
Correct Answer:
Response
Feedback:
What is the conjugate acid of HCO
3
-
?
H
2
CO
3
H
2
CO
3
An acid donates a proton which is accepted by the lone pair of the
base.
Therefore,
the substance with the added proton is the
conjugate
acid.
1 out of 1 points
1 out of 1 points
1 out of 1 points
Question 11
Selected Answer:
4.66
Correct Answer:
4.66 ± 0.02
Response
Feedback:
What is the expected pH of a nitric acid solution , HNO
3
, with a concentration of 2.21 x 10
-5
M?
Enter your answer in decimal format with two decimal places (value ± 0.02).
Practice Exam 2.2
Practice Exam 2.2
Question 12
Selected Answer:
Correct Answer:
Use the following table of data in answering the question below the table:
Acid Name
Formula
pK
a
pK
b
Conjugate
Base
Hydrofluoric acid
HF
3.17
10.83
F
-
Nitrous acid
HNO
2
3.25
10.75
NO
2
-
Hypochlorous acid
HOCl
7.54
6.46
OCl
-
Hypobromous acid
HOBr
8.62
5.38
OBr
-
Hydrocyanic acid
HCN
9.21
4.79
CN
-
Ammonium
NH
4
+
9.24
4.76
NH
3
The acid HN
3
has a pK
a
of 4.72. How many of the conjugate bases shown in the table are stronger
bases than the base N
3
-
?
4
4
1 out of 1 points
1 out of 1 points
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Response
Feedback:
Practice exam 2.4
Practice exam 2.4
Question 13
Selected Answer:
12.34
Correct Answer:
12.34 ± 0.02
Response
Feedback:
At 25º C , what is the pH of a solution prepared by dissolving 0.00823 mol of Ca(OH)
2
in water to give
756.5 mL of solution?
Enter your answer in decimal format with two decimal places (value ± 0.02).
Practice exam 2 5
Practice exam 2 5
Question 14
A weak acid, HA, is dissolved in water given a solution concentration of 0.152 M. The percent dissociation
(ionization) is measured and found to be 8.4%. Based on these data, what is the value of K
a
for this weak
acid?
1 out of 1 points
1 out of 1 points
Selected Answer:
1.17E-3
Correct Answer:
1.17E-3 ± 5%
Response
Feedback:
Enter your answer in exponential format using a capital "E"
(example 1.23E-4) and no units (value ± 5%).
Practice exam 2 6
Practice exam 2 6
Question 15
Selected Answer:
12.26
Correct Answer:
12.27 ± 0.02
Response
Feedback:
Calculate the pH of a 0.362 M solution of a base with a base dissociation constant of K
b
= 9.78 x 10
-4
.
Enter your answer in decimal format with two decimal places (value ± 0.02).
Practice exam 2 7
Practice exam 2 7
1 out of 1 points
Question 16
Selected Answer:
11.12
Correct Answer:
11.12 ± 0.02
Response
Feedback:
At 25º C, what is the pOH of a buÖer that consists of 0.651 M HA and 0.472 M NaA?
HA represents a weak acid with a K
a
of is 9.45 x 10
-4
and NaA represents the conjugate base.
Enter your answer in decimal format with two decimal places (value ± 0.02). Practice exam 2 8
Practice exam 2 8
Question 17
Selected Answer:
8.16
Correct Answer:
8.16 ± 0.02
Response
Feedback:
At 25º C, what is the pH of a 0.152 M aqueous solution of potassium Òuoride (KF) given that the K
a
of
hydroÒuoric acid (HF) is 7.24 x 10
-4
.
Enter your answer in decimal format with two decimal places (value ± 0.02).
1 out of 1 points
1 out of 1 points
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Practice exam 2 9
Practice exam 2 9
Question 18
Selected Answer:
False
Correct Answer:
False
Response
Feedback:
True or false:
The pH at the equivalence point is always pH = 7.
If a weak acid is titrated with a strong base, at the equivalence point, the pH will be greater
than 7, (pH > 7).
If a strong acid is titrated with a strong base, at the equivalence point, the pH will be equal
to 7, (pH = 7).
If a weak base is titrated with a strong acid, at the equivalence point, the pH will be less
than 7, (pH < 7).
Practice exam 2.10
Practice exam 2.10
Question 19
1 out of 1 points
1 out of 1 points
Selected Answer:
25.51
Correct Answer:
25.51 ± 1%
Response
Feedback:
Determine the volume in mL of 0.378 M HClO
4
(aq) needed to reach the half-equivalence (stoichiometric)
point in the titration of 53.71 mL of 0.359 M ammonia, NH
3
. The K
b
of ammonia is 1.8 x 10
-5
.
Enter your answer in decimal format with two decimal places (value ±1%).
Practice Exam 2 11
Practice Exam 2 11
Question 20
Selected Answer:
4.07
Correct Answer:
4.07 ± 0.02
Response
Feedback:
A 25.00 mL sample of 0.150 M monoprotic organic acid is titrated with aqueous sodium hydroxide. After
6.42 mL of 0.150 M NaOH is added, what is the pH of the solution?
The K
a
of the acid is 2.97 x 10
-5
.
Enter your answer in decimal format with two decimal places (value ± 0.02).
1 out of 1 points
Practice Exam 2 12
Practice Exam 2 12
Question 21
Selected Answer:
10.42
Correct Answer:
10.61 ± 0.04
Response
Feedback:
One liter of a buÖer is prepared with concentrations of 0.250 M C
2
H
5
NH
2
and 0.250 M C
2
H
5
NH
3
Cl. If
2.13 g of NaOH is then added, what is the resulting pH?
Assume the solution volume does not change
and that K
b
of C
2
H
5
NH
2
is 2.64 x 10
-4
.
Enter your answer in decimal format with two decimal places (value ± 0.04).
Practice exam 2 13
Practice exam 2 13
Question 22
0 out of 1 points
1 out of 1 points
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Thursday, May 6, 2021 3:37:55 PM CDT
Selected Answer:
5.55
Correct Answer:
5.55 ± 0.02
Response
Feedback:
The weak base methylamine, CH
3
NH
2
, is titrated with HI
. What is the pH at the equivalence point, if the
concentration of methylammonium iodide, CH
3
NH
3
I
, is known to be 0.348 M?
The K
b
of CH
3
NH
2
is 4.4 x 10
-4
.
Enter your answer in decimal format with two decimal places (value ± 0.02).
Practice exam 2 14
Practice exam 2 14
←
OK
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AIV-20: Getting Connected (Writing lonic Compounds)
Part 1: Putting together lonic Compounds
lonic compound
Metal
Number of
cation
nonmetal
number of
anion
total
total charge = 0
valence
valence
number of
electrons
electrons
valence
electrons
NaF, sodium fluoride
Na
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F-
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Mg
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Using a chemical equation to find moles of product from moles ...
with
Ammonium phosphate ((NH4), PO4)
is an important ingredient in many solid fertilizers. It can be made by reacting aqueous phosphoric acid (H, PO,)
liquid ammonia. Calculate the moles of ammonium phosphate produced by the reaction of 0.10 mol of ammonia. Be sure your answer has a unit symbol, if
necessary, and round it to the correct number of significant digits.
Explanation
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Using the balanced equation for the combustion of ethanol:
C2H60+302 -> 2CO2+3H20
a.How many grams of CO2 are formed from 0,50mol of ethanol?
ww
b.How many moles of H20 are formed from 24 g of ethanol?
c.How many grams of 02 are needed to react with 0.25 mol of ethanol? 24
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The Perlodic Table of the Elements
Elements in the same group tend to have similar characteristics, but some things like tendency to gain or lose electrons can still vary
even within a group Which of the following is true regarding the elements in group 2?
O A Be, Beryllium is the largest and has the greatest tendency to gain electrons.
OB Be Beryllium and Ba, Barium will have the same tendancy to lose electrons
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6. Draw the arrow-pushing mechanism and propose the product(s). When appropriate, make
sure to indicate the appropriate stereo-/regio-chemistry of the product(s). Note that the
mechanism(s) by which the product(s) form in reactions A and B are shown in pink. For
reactions C, D, and E you need to deduce the mechanism by carefully analyzing your
reagents and conditions.
A.
Br
OH
E1 and SN1
B.
H₂O
SN1
Hint: A mixture of two allylic alcohols forms.
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Solving moles-to-moles limiting reactant problems
Nitrogen dioxide (NO2) gas and liquid water (H,O)
react to form aqueous nitric acid (HNO,) and nitrogen monoxide (NO)gas. Suppose you have 2.0 mol of
NO, and 5.0 mol of H,O in a reactor.
Calculate the largest amount of HNO, that could be produced. Round your answer to the nearest 0.1 mol.
| mol
Explanation
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Calculating partial pressure in a gas mixture
Jacqueline
A 5.00 L tank at 7.37 °C is filled with 18.2 g of chlorine pentafluoride gas and 3.28 g of boron trifluoride gas. You can assume both gases behave as ideal gases
under these conditions.
Calculate the mole fraction and partial pressure of each gas, and the total pressure in the tank. Round each of your answers to 3 significant digits.
圖
mole fraction:
chlorine pentafluoride
partial pressure:
| atm
mole fraction:
boron trifluoride
partial pressure:
| atm
Total pressure in tank:
| atm
Explanation
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Arial
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III I
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I 7 II I|
.1. Refer to the table of standard reduction potentials.
Standard Reduction Potentials at 25 C
Reduction Half-Reaction
(V)
FAg + 2 €
H2O{aq) + 2 H*(aq)+ 2 6
Mno,taq) + 8 H*(aq) + 5 &
Clalg) + 2 e
CrOFMaq)+ 14 H*(aq) + 6 6-
Ozlg + 4 H*(aq) + 4 &
Bra() + 26
Ag*(aq) + e
Fe*(aq) + e
Ozl9) + 2 H'(aq) + 2 €
2(s)+ 26
Ozlg) + 2 HO) + 46
Cu (aq) + 2 €
Sn" (ag)+ 2 6
2 P(aq)
2 H2O()
→ Mn(aq) + 4 H;0()
→2 cr(aq)
2 Cr (aq)+ 7 H0()
→2 HO()
2 Br(aq)
Ag(s)
» Fe*(aq)
→H;Oz(aq)
→2 F(aq)
→4 OH"(aq)
2.87
1.78
1.51
1.36
1.33
3.
1.23
1.09
0.80
0.77…
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A ALEKS - Esther Octave Learn X
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Esther
Calculating the wavelength of a spectral line from an energy..
-21
". You can find the meaning of
This energy diagram shows the allowed energy levels of an electron in a certain atom. (Note: the SI prefix 'zepto' means 10
any SI prefix in the ALEKS Data tab.)
1400 -
1200 -
-C
dlo
1000 -
800
Ar
energy (z)
B
600 -
-A
400.
200-
Use this diagram to complete the table below.
What is the energy of the electron in the ground state?
What is the energy of the electron in the first excited
state?
O absorbed
If the electron makes the transition shown by the red
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1
III I
III 1 I
2
3 1
I 4
5 II II
6 1
III |
.5.
For a reaction in which E° = -0.100 V and n = 1 mol electrons / mol, calculate AG°. State
+
your assumptions, if any, about temperature.
.6.
For a reaction in which E° = 0.100 V andn = 1 mol electrons / mol, calculate AG° at 25°C.
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MnO, (aq) + 8H*(aq) + 5e → Mn²*(aq) + 4 H,O(1)
Al(s) → Alš*(aq) + 3 e
+
.ЗА.
Assign oxidation numbers to all metals whether they be elemental, monatomic ion, or in
a polyatomic ion, in questions (1) and (2),
.3B. Tell what is being oxidized and what is being reduced in each reaction in questions (1) and
(2).
.3C. Identify each half-reaction in question (2) as oxidation half-reaction or reduction
half-reaction.
.4. Do you need to know the temperature to calculate AG° from E°? Explain.
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Kayley v
A chemist v v
as a safety inspector finds an unmarked bottle in a lab cabinet. A note on the door of the cabinet says the cabinet is used to store bottles of
pentane, dimethyl sulfoxide, acetone, methyl acetate, and chloroform.
The chemist plans to try to identify the unknown liquid by measuring the density and comparing to known densities. First, from his collection of Material Safety
Data Sheets (MSDS), the chemist finds the following information:
liquid
density
0.63
mL
pentane
db
dimethyl sulfoxide
1.1
0.79
acetone
0.93
mL
methyl acetate
1.5
chloroform
3
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It takes 155 s for an unknown gas to effuse through a porous wall and 97 s for the same volume of N2
gas to effuse at the same temperature and pressure. What is the molar mass of the unknown gas?
g/mol
...
115
MAR
1664
18
ottv A
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Vidya lit a candle and covered it with a glass.
The candle burned for some time and then went
off. She wanted to check whether the length of
the candle would affect the time for which it
burns. She performed the experiment again after
changing something.
Which of these would be the correct
experimental setup for her to use? * (1 Point)
She wanted to check whether the length of the candle would affect the time for which it burns.
She performed the experiment again after changing something.
Which of these would be the correct experimental setup for her to use?
A
Longer candle;
No glass
C
B
Longer candle;
Longer glass
D
D
B
Longer candle;
Same glass
Same candle;
Longer glass
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