PiQ Exam 2

pdf

School

University of Houston *

*We aren’t endorsed by this school

Course

1332

Subject

Chemistry

Date

Apr 3, 2024

Type

pdf

Pages

13

Uploaded by CorporalCatPerson859

Report
Review Test Submission: Additional Practice Exam 2 with feedback ( A Remix) 2021SP-22142-CHEM1332-Fundamentals of Chemistry 2 Course Content Folders ... Prior weeks' PiQs Review Test Submission: Additional Practice Exam 2 with feedback ( A Remix) User Course 2021SP-22142-CHEM1332-Fundamentals of Chemistry 2 Test Additional Practice Exam 2 with feedback ( A Remix) Started 4/2/21 5:36 PM Submitted 4/2/21 6:40 PM Status Completed Attempt Score 21 out of 22 points Time Elapsed 1 hour, 3 minutes out of 1 hour and 23 minutes Instructions For multiple choice questions, select the best answer from those provided. For Ñll-in the blank questions, spelling counts, and atomic symbols must start with capital letters. For numerical entry problems: The default scoring method checks that your input value agrees within plus or minus 2% of the expected value. Therefore unless otherwise speciÑed, you should report at least three signiÑcant Ñgures and enter your value with no units. Some questions may ask you to enter your answer in scientiÑc notation. This must be done as exponential notation, using a capital "E" . For example, 1921 would be entered as 1.921 E 3; 0.00789 would be 7.89 E -3. Some questions may specify the number of decimal places to be used for an answer. For example, the value 6789.123 has three decimal places. Some questions may specify that the log-base 10 of the calculated values should be entered as the answer with at least two decimal places. For example, a calculated value of 0.00789 would be entered as log(0.00789) = -2.103. If an image doesn't appear, try reloading the question using the reload icon (i.e. circular arrow) at the top of the Browser. Please read and answer each question carefully following any formatting instructions given: Library Writing Center Launch lp Home
Results Displayed Submitted Answers, Correct Answers, Feedback Question 1 Selected Answer: Correct Answer: Response Feedback: The molecular geometry of the XeF 4 molecule is ________, and this molecule is ________. square planar, nonpolar square planar, nonpolar (Hint: start by drawing the Lewis dot structure, use the electronegativity difference to determine the bond polarity, and finally consider how the dipoles (vectors) combine to determine the overall molecular polarity.) Question 2 Selected Answer: Correct Answer: Response Feedback: Consider the following reaction and its equilibrium constant: 4 CuO(s) + CH 4 (g) CO 2 (g) + 4 Cu(s) + 2 H 2 O(g) K c = 1.10 A reaction mixture contains 0.22 M CH 4 , 0.67 M CO 2 and 1.3 M H 2 O. Which of the following statements is TRUE concerning this system? The reaction will shift in the direction of reactants. The reaction will shift in the direction of reactants. IF Q > K reverse direction 1 out of 1 points 1 out of 1 points
Q = K at equilibrium Q < K forward direction Question 3 Selected Answer: 2.51E0 Correct Answer: 2.51E0 ± 2% Response Feedback: At a given temperature, the K eq for the equilibrium below is 0.399. SO 2 (g) + O 2 (g) SO 3 (g) What is the value of K eq at this temperature for the following reaction? SO 3 (g) SO 2 (g) + O 2 (g) If you multiply an equation by a number, you raise the equilibrium constant to that power. If you reverse a reaction, you take the reciprocal of the equilibrium constant. If you add two equations, you multiply their equilibrium constants. Question 4 Selected Answer: 6.18E-2 Correct Answer: 6.18E-2 ± 2% Response Feedback: Given the following reaction at equilibrium, if K p = 2.45 at 210 °C, K c = ________. PCl 5 (g) PCl 3 (g) + Cl 2 (g) , with R = 0.0821 atm L / (mol K) and T in K. Question 5 Selected Answer: 3.73E-5 At a given temperature, the reaction, H 2 (g) + I 2 (g) 2HI (g), has a value of K eq = 771. If the hydrogen concentration is 0.00541 M and the hydrogen iodide concentration is 0.01248 M, what is the molar concentration of the iodine at equilibrium? 1 out of 1 points 1 out of 1 points 1 out of 1 points
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
Correct Answer: 3.73E-5 ± 2% Response Feedback: The equilibrium constant is equal to the products over the reactants raised to the stoichiometric ccoeÔcients (leaving out pure liquids and solid). Once your write the equilibrium equation, you then substitute in the given values and solved for the unknown concentration. Question 6 Selected Answer: 9.352E1 Correct Answer: 9.35E1 ± 2 Response Feedback: Iodine and bromine react as shown below: I 2 (g) + Br 2 (g) 2IBr (g). If 0.531 mol of I 2 and 0.531 mol of Br 2 are placed into a sealed 1.00 L Òask, and at equilibrium the Òask contains 0.88 mol of IBr, what is the value of the equilibrium constant, K eq ? (Hint: you will needed to Ñgure out the amounts of each substance at equilibrium using stoichiometry, before you can substitute into the equilibrium expression. An ICE table can help you organize this type of data. ) First calculate the concentrations at equilibrium using stoichiometry. They substitute the concentrations into the equilibrium expression to Ñnd the value of K eq . Question 7 Selected Answer: Correct Answer: Response Feedback: The equilibrium constant is given for two of the reactions below. Determine the value of the missing equilibrium constant. A(g) + 2B(g) AB 2 (g) Kc = 59 AB 2 (g) + B(g) AB 3 (g) K c = ? A(g) + 3B(g) AB 3 (g) K c = 478 8.1 8.1 If you multiply an equation by a number, you raise the equilibrium constant to that power. If you reverse a reaction, you take the reciprocal of the equilibrium constant. If you add two equations, you multiply their equilibrium constants. 1 out of 1 points 1 out of 1 points
Question 8 Selected Answer: Correct Answer: Response Feedback: Consider the following reaction at equilibrium. What eÖect will adding some graphite have on the system? CO 2 (g) + C(graphite) 2 CO(g) No eÖect will be observed since C is not included in the equilibrium expression. No eÖect will be observed since C is not included in the equilibrium expression. Because the equilibrium is heterogeneous, the solid does not appear in the equilibrium expression and therefore adding and subtracting graphite will not shift the equilibrium. Question 9 Selected Answer: Correct Answer: Response Feedback: An aqueous solution of ________ will produce an acidic solution. NH 4 NO 3 NH 4 NO 3 Conjugate bases of strong acids are neutral (i.e. not bases). (Based on the list of seven strong acids, this mean the ions HSO 4 - , NO 3 - , I - , Br - , Cl - , ClO 3 - , and ClO 4 - can form neutral salts. Group I and II cations form neutral salts, but since ammonium is the conjugate base of a weak acid (ammonia) it forms an acidic salt. Anions that are conjugate bases of weak acids form basic salts. Question 10 Selected Answer: Correct Answer: Response Feedback: What is the conjugate acid of HCO 3 - ? H 2 CO 3 H 2 CO 3 An acid donates a proton which is accepted by the lone pair of the base. Therefore, the substance with the added proton is the conjugate acid. 1 out of 1 points 1 out of 1 points 1 out of 1 points
Question 11 Selected Answer: 4.66 Correct Answer: 4.66 ± 0.02 Response Feedback: What is the expected pH of a nitric acid solution , HNO 3 , with a concentration of 2.21 x 10 -5 M? Enter your answer in decimal format with two decimal places (value ± 0.02). Practice Exam 2.2 Practice Exam 2.2 Question 12 Selected Answer: Correct Answer: Use the following table of data in answering the question below the table: Acid Name Formula pK a pK b Conjugate Base Hydrofluoric acid HF 3.17 10.83 F - Nitrous acid HNO 2 3.25 10.75 NO 2 - Hypochlorous acid HOCl 7.54 6.46 OCl - Hypobromous acid HOBr 8.62 5.38 OBr - Hydrocyanic acid HCN 9.21 4.79 CN - Ammonium NH 4 + 9.24 4.76 NH 3 The acid HN 3 has a pK a of 4.72. How many of the conjugate bases shown in the table are stronger bases than the base N 3 - ? 4 4 1 out of 1 points 1 out of 1 points
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
Response Feedback: Practice exam 2.4 Practice exam 2.4 Question 13 Selected Answer: 12.34 Correct Answer: 12.34 ± 0.02 Response Feedback: At 25º C , what is the pH of a solution prepared by dissolving 0.00823 mol of Ca(OH) 2 in water to give 756.5 mL of solution? Enter your answer in decimal format with two decimal places (value ± 0.02). Practice exam 2 5 Practice exam 2 5 Question 14 A weak acid, HA, is dissolved in water given a solution concentration of 0.152 M. The percent dissociation (ionization) is measured and found to be 8.4%. Based on these data, what is the value of K a for this weak acid? 1 out of 1 points 1 out of 1 points
Selected Answer: 1.17E-3 Correct Answer: 1.17E-3 ± 5% Response Feedback: Enter your answer in exponential format using a capital "E" (example 1.23E-4) and no units (value ± 5%). Practice exam 2 6 Practice exam 2 6 Question 15 Selected Answer: 12.26 Correct Answer: 12.27 ± 0.02 Response Feedback: Calculate the pH of a 0.362 M solution of a base with a base dissociation constant of K b = 9.78 x 10 -4 . Enter your answer in decimal format with two decimal places (value ± 0.02). Practice exam 2 7 Practice exam 2 7 1 out of 1 points
Question 16 Selected Answer: 11.12 Correct Answer: 11.12 ± 0.02 Response Feedback: At 25º C, what is the pOH of a buÖer that consists of 0.651 M HA and 0.472 M NaA? HA represents a weak acid with a K a of is 9.45 x 10 -4 and NaA represents the conjugate base. Enter your answer in decimal format with two decimal places (value ± 0.02). Practice exam 2 8 Practice exam 2 8 Question 17 Selected Answer: 8.16 Correct Answer: 8.16 ± 0.02 Response Feedback: At 25º C, what is the pH of a 0.152 M aqueous solution of potassium Òuoride (KF) given that the K a of hydroÒuoric acid (HF) is 7.24 x 10 -4 . Enter your answer in decimal format with two decimal places (value ± 0.02). 1 out of 1 points 1 out of 1 points
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
Practice exam 2 9 Practice exam 2 9 Question 18 Selected Answer: False Correct Answer: False Response Feedback: True or false: The pH at the equivalence point is always pH = 7. If a weak acid is titrated with a strong base, at the equivalence point, the pH will be greater than 7, (pH > 7). If a strong acid is titrated with a strong base, at the equivalence point, the pH will be equal to 7, (pH = 7). If a weak base is titrated with a strong acid, at the equivalence point, the pH will be less than 7, (pH < 7). Practice exam 2.10 Practice exam 2.10 Question 19 1 out of 1 points 1 out of 1 points
Selected Answer: 25.51 Correct Answer: 25.51 ± 1% Response Feedback: Determine the volume in mL of 0.378 M HClO 4 (aq) needed to reach the half-equivalence (stoichiometric) point in the titration of 53.71 mL of 0.359 M ammonia, NH 3 . The K b of ammonia is 1.8 x 10 -5 . Enter your answer in decimal format with two decimal places (value ±1%). Practice Exam 2 11 Practice Exam 2 11 Question 20 Selected Answer: 4.07 Correct Answer: 4.07 ± 0.02 Response Feedback: A 25.00 mL sample of 0.150 M monoprotic organic acid is titrated with aqueous sodium hydroxide. After 6.42 mL of 0.150 M NaOH is added, what is the pH of the solution? The K a of the acid is 2.97 x 10 -5 . Enter your answer in decimal format with two decimal places (value ± 0.02). 1 out of 1 points
Practice Exam 2 12 Practice Exam 2 12 Question 21 Selected Answer: 10.42 Correct Answer: 10.61 ± 0.04 Response Feedback: One liter of a buÖer is prepared with concentrations of 0.250 M C 2 H 5 NH 2 and 0.250 M C 2 H 5 NH 3 Cl. If 2.13 g of NaOH is then added, what is the resulting pH? Assume the solution volume does not change and that K b of C 2 H 5 NH 2 is 2.64 x 10 -4 . Enter your answer in decimal format with two decimal places (value ± 0.04). Practice exam 2 13 Practice exam 2 13 Question 22 0 out of 1 points 1 out of 1 points
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
Thursday, May 6, 2021 3:37:55 PM CDT Selected Answer: 5.55 Correct Answer: 5.55 ± 0.02 Response Feedback: The weak base methylamine, CH 3 NH 2 , is titrated with HI . What is the pH at the equivalence point, if the concentration of methylammonium iodide, CH 3 NH 3 I , is known to be 0.348 M? The K b of CH 3 NH 2 is 4.4 x 10 -4 . Enter your answer in decimal format with two decimal places (value ± 0.02). Practice exam 2 14 Practice exam 2 14 OK