c) ogenase reducing acetaldehyde to ethanol, NADH donates a hydride to the carbonyl C, and the oxyanion is transiently stabilized by the Zn2+ divalent cation (see figure on first page), which is then protonated to form the final product. If one assumes that 4-iodopyrazole was bound similarly to the substrate, then which atoms of the inhibitor would be equivalent to the atoms of acetaldehyde? Mark the figure below with the atom of 4-iodopyrazole equivalent to each of the 3 heavy atoms in acetaldehyde. (Use the atom identifiers to identify each one unambiguously: N1, N2, C3, C4, C5, 14.) carbonyl C HC carbonyl O CH3 methyl C
c) ogenase reducing acetaldehyde to ethanol, NADH donates a hydride to the carbonyl C, and the oxyanion is transiently stabilized by the Zn2+ divalent cation (see figure on first page), which is then protonated to form the final product. If one assumes that 4-iodopyrazole was bound similarly to the substrate, then which atoms of the inhibitor would be equivalent to the atoms of acetaldehyde? Mark the figure below with the atom of 4-iodopyrazole equivalent to each of the 3 heavy atoms in acetaldehyde. (Use the atom identifiers to identify each one unambiguously: N1, N2, C3, C4, C5, 14.) carbonyl C HC carbonyl O CH3 methyl C
Biochemistry
6th Edition
ISBN:9781305577206
Author:Reginald H. Garrett, Charles M. Grisham
Publisher:Reginald H. Garrett, Charles M. Grisham
Chapter17: Metabolism: An Overview
Section: Chapter Questions
Problem 14P
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