Based on the following 1H NMR spectra for LDA. Need help calculating the large and small coupling constants. Batch 3Sample 6BRUKERCurrent Data ParametersNAMEEXPNOPROCNO3rdyr-2105261CH3F2 - Acquisition ParametersDate_Time2021052612.08 h„CH3INSTRUMspectPROBHDz104450_0319 (CH3zg3065536CDC131628012.820 Hz0.244532 Hz4.0894465 sec3262.400 usec17.77 usec298.2 K1.00000000 sec1400.1324708 MHzPULPROGTDSOLVENTNSDSHMSFIDRESAQRG8.48.28.07.87.67.47.27.0рpmDWDETED1TDOSFO1NUC1POP1PLW11H3.33 usec10.00 usec15.00000000 wF2 - Processing parameters65536400.1300891 MHzSISFWDWSBEMLB0.30 HzGBPC1.008.762ppmLO96'00.8700'L

The splitting of the signal containing the two adjacent peaks gives the coupling constant (J) value.…

Current Data Parameters NAME EXPNO PROCNO 3rdyr-210526 6 1 CH3 CH F2 - Acquisition Parameters Date Time 20210526 12.08 h INSTRUM PROBHD PULPROG apect z104450_0319 ( zg30 65536 CDC13 16 2 8012.820 Hz 0.244532 Hz CH3 TD SOLVENT NS DS CI SWH FIDRES 4.0894465 sec 32 62.400 usec 17.77 usec 298.2 K 1.00000000 sec 1 400.1324708 MHz AQ RG DW DE 8.4 8.2 8.0 7.8 7.6 7.4 7.2 7.0 ppm TE D1 TDO SFO1 NUC1 PO P1 PLW1 1H 3.33 usec 10.00 usec 15.0000000 w F2 - SI SF WDW SSB Processing parameters 65536 400.1300891 MHz EM 0.30 Hz LB GB PC 1.00 8 7 5 4 3 2 1 ppm 96'0 0.87 00'L

Current Data Parameters NAME EXPNO PROCNO 3rdyr-210526 6 1 CH3 CH F2 - Acquisition Parameters Date Time 20210526 12.08 h INSTRUM PROBHD PULPROG apect z104450_0319 ( zg30 65536 CDC13 16 2 8012.820 Hz 0.244532 Hz CH3 TD SOLVENT NS DS CI SWH FIDRES 4.0894465 sec 32 62.400 usec 17.77 usec 298.2 K 1.00000000 sec 1 400.1324708 MHz AQ RG DW DE 8.4 8.2 8.0 7.8 7.6 7.4 7.2 7.0 ppm TE D1 TDO SFO1 NUC1 PO P1 PLW1 1H 3.33 usec 10.00 usec 15.0000000 w F2 - SI SF WDW SSB Processing parameters 65536 400.1300891 MHz EM 0.30 Hz LB GB PC 1.00 8 7 5 4 3 2 1 ppm 96'0 0.87 00'L

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter7: Statistical Data Treatment And Evaluation

Section: Chapter Questions

Problem 7.10QAP

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