Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 1, Problem 1.54E
Under what conditions of temperature does a Redlich-Kwong gas behave like an ideal gas? Use the Redlich-Kwong equation of state to justify your answer.
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Chapter 1 Solutions
Physical Chemistry
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- Numerically evaluate for one mole of methane acting as a van der Waals gas at a T = 298 K and V = 25.0 L and b T = 1000 K and V = 250.0 L. Comment on which set of conditions yields a number closer to that predicted by the ideal gas law. pVT,narrow_forwardWhy is equation2.37 written interms of CV and Cp and not c-v and c-p ?arrow_forwardWhat properties of a nonideal gas do the Vander Waals constants represent?arrow_forward
- Under what conditions of volume does a van der Waals gas behave like an ideal gas? Use the van der Waals equation of state to justify your answer.arrow_forwardUnder what conditions would the van der Waals constant b be negative? Do you think there are any gases for which this occurs?arrow_forwardTable 1.4 show that the second virial coefficient B for He is negative at low temperature, seems to maximize at a little over 12.0 cm3/mol, and then decreases. Do you think it will become negative again at higher temperatures? Why is it decreasing?arrow_forward
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