Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
Question
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Chapter 1, Problem 1.75E
Interpretation Introduction

(a)

Interpretation:

The expected for translational and rotational motions, in RT units, for the gas Ne is to be calculated.

Concept introduction:

Generally, the movement of atoms and molecules is denoted in terms of the degree of freedom they have. It is defined as the number of independent parameters required to describe the state of the molecule completely. Thus, the motion of a molecule is given as 1) translation 2) rotational 3) vibration and they can be expressed in terms of degrees of freedom.

Interpretation Introduction

(b)

Interpretation:

The expected for translational and rotational motions, in RT units, for the gas HCl is to be calculated.

Concept introduction:

Generally, the movement of atoms and molecules is denoted in terms of the degree of freedom they have. It is defined as the number of independent parameters required to describe the state of the molecule completely. Thus, the motion of a molecule is given as 1) translation 2) rotational 3) vibration and they can be expressed in terms of degrees of freedom.

Interpretation Introduction

(c)

Interpretation:

The expected for translational and rotational motions, in RT units, for the gas C2H2 is to be calculated.

Concept introduction:

Generally, the movement of atoms and molecules is denoted in terms of the degree of freedom they have. It is defined as the number of independent parameters required to describe the state of the molecule completely. Thus, the motion of a molecule is given as 1) translation 2) rotational 3) vibration and they can be expressed in terms of degrees of freedom.

Interpretation Introduction

(d)

Interpretation:

The expected for translational and rotational motions, in RT units, for the gas CH4 is to be calculated.

Concept introduction:

Generally, the movement of atoms and molecules is denoted in terms of the degree of freedom they have. It is defined as the number of independent parameters required to describe the state of the molecule completely. Thus, the motion of a molecule is given as 1) translation 2) rotational 3) vibration and they can be expressed in terms of degrees of freedom.

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Determine the number of degrees of freedom (trans + rot) for each of the following gases; Ne, CO2,Ā H2O. Then calculate the average total kinetic energy (per mole) at 25 celsius for each gas
21.2b The best laboratory vacuum pump can generate a vacuum of about 1 nTorr. At 25Ā°C and assuming that air consists of N2 molecules with a collision diameter of 395 pm, calculate (a) the mean speed of the molecules, (b) the mean free path, (c) the collision frequency in the gas.
Assuming it behaves as an ideal gas, calculate the temperature of HCl if it has an average translational kinetic energy of 6970 J/mol.

Chapter 1 Solutions

Physical Chemistry

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