Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 10, Problem 10.27E
Interpretation Introduction

(a)

Interpretation:

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0to0.02a is to be calculated.

Concept introduction:

For the normalization of the wavefunction, the wavefunction is integrated as a product of its conjugate over the entire limits. It is expressed by the equation as given below.

0(NΨ)(NΨ*)=1

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

Expert Solution
Check Mark

Answer to Problem 10.27E

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0to0.02a is 2.10×104.

Explanation of Solution

For the probability of the wavefunction the expression is as follows.

0(NΨ)(NΨ*)=P

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

P is the probability.

Substitute the values in the above equation as follows.

P=00.02a(Ψ)(Ψ*)dx=00.02a(2asin2πxa)(2asin2πxa)dx=2a00.02a(sin2πxa)(sin2πxa)dx=2a00.02a(sin2πxa)2dx

The above equation is simplified as given below.

=2a00.02a(sin22πxa)dx=2a×[x2a8πsin4πxa]00.02a=2a×[(0.02a2a8πsin4π(0.02a)a)0]=2a×(0.02a2a8πsin0.08π)

=2a×(0.02a2a25.12sin(0.2512))=2a×(0.02a20.24856a25.12)=2a×0.0053a50.24=2.10×104

Conclusion

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0to0.02a is calculated as 2.10×104.

Interpretation Introduction

(b)

Interpretation:

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.24ato0.26a is to be calculated.

Concept introduction:

For the normalization of the wavefunction, the wavefunction is integrated as a product of its conjugate over the entire limits. It is expressed by the equation as given below.

0(NΨ)(NΨ*)=1

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

Expert Solution
Check Mark

Answer to Problem 10.27E

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.24ato0.26a is 0.075.

Explanation of Solution

For the probability of the wavefunction the expression is as follows.

0(NΨ)(NΨ*)=P

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefuction.

P is the probability.

Substitute the values in the above equation as follows.

P=0.24a0.26a(Ψ)(Ψ*)dx=0.24a0.26a(2asin2πxa)(2asin2πxa)dx=2a0.24a0.26a(sin2πxa)(sin2πxa)dx=2a0.24a0.26a(sin2πxa)2dx

The above equation is simplified as follows.

=2a0.24a0.26a(sin22πxa)dx=2a×[x2a8πsin4πxa]0.24a0.26a=2a×[(0.26a2a8πsin4π(0.26a)a)(0.24a2a8πsin4π(0.24a)a)]=2a×(0.26a20.24a2a8πsin1.04π+a8πsin0.81π)

=2a×(0.26a20.24a2a8πsin1.04π+a8πsin0.81π)=2a×(0.02a2+0.68683a25.12)=2a×(1.87606a)50.24=0.075

Conclusion

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.24ato0.26a is calculated as 0.075.

Interpretation Introduction

(c)

Interpretation:

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.49ato0.51a is to be calculated.

Concept introduction:

For the normalization of the wavefunction, the wavefunction is integrated as a product of its conjugate over the entire limits. It is expressed by the equation as given below.

0(NΨ)(NΨ*)=1

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

Expert Solution
Check Mark

Answer to Problem 10.27E

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.49ato0.51a is 4.9×103.

Explanation of Solution

For the probability of the wavefunction the expression is as follows.

0(NΨ)(NΨ*)=P

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

P is the probability.

Substitute the values in the above equation as follows.

P=0.49a0.51a(Ψ)(Ψ*)dx=0.49a0.51a(2asin2πxa)(2asin2πxa)dx=2a0.49a0.51a(sin2πxa)(sin2πxa)dx=2a0.49a0.51a(sin2πxa)2dx

The above equation is simplified as follows.

=2a0.49a0.51a(sin22πxa)dx=2a×[x2a8πsin4πxa]0.49a0.51a=2a×[(0.51a2a8πsin4π(0.51a)a)(0.49a2a8πsin4π(0.49a)a)]=2a×(0.51a20.49a2a8πsin2.04π+a8πsin1.96π)

=2a×(0.51a20.49a2a8πsin2.04π+a8πsin1.96π)=2a×(0.02a20.189605a25.12)=2a×0.12319a50.24=4.9×103

Conclusion

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.49ato0.51a is calculated as 4.9×103.

Interpretation Introduction

(d)

Interpretation:

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.74ato0.76a is to be calculated.

Concept introduction:

For the normalization of the wavefunction, the wavefunction is integrated as a product of its conjugate over the entire limits. It is expressed by the equation as given below.

0(NΨ)(NΨ*)=1

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

Expert Solution
Check Mark

Answer to Problem 10.27E

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.74ato0.76a is 0.047.

Explanation of Solution

For the probability of the wavefunction the expression is as follows.

0(NΨ)(NΨ*)=P

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

P is the probability.

Substitute the values in the above equation as follows.

P=0.74a0.76a(Ψ)(Ψ*)dx=0.74a0.76a(2asin2πxa)(2asin2πxa)dx=2a0.74a0.76a(sin2πxa)(sin2πxa)dx=2a0.74a0.76a(sin2πxa)2dx

The above equation is simplified as given below.

=2a0.74a0.76a(sin22πxa)dx=2a×[x2a8πsin4πxa]0.74a0.76a=2a×[(0.76a2a8πsin4π(0.76a)a)(0.74a2a8πsin4π(0.74a)a)]=2a×(0.76a20.74a2a8πsin3.04π+a8πsin2.96π)

=2a×(0.76a20.74a2a8πsin3.04π+a8πsin2.96π)=2a×(0.02a2+0.337955a25.12)=2a×1.17831a50.24=0.047

Conclusion

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.74ato0.76a is calculated as 0.047.

Interpretation Introduction

(e)

Interpretation:

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.98ato1.00a is to be calculated. The graph of probabilities versus x is to be plotted.

Concept introduction:

For the normalization of the wavefunction, the wavefunction is integrated as a product of its conjugate over the entire limits. It is expressed by the equation as given below.

0(NΨ)(NΨ*)=1

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

Expert Solution
Check Mark

Answer to Problem 10.27E

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.98ato1.00a is 9.75×103.The graph of probabilities versus x is given below.

Physical Chemistry, Chapter 10, Problem 10.27E , additional homework tip  1

Explanation of Solution

For the probability of the wavefunction the expression is as follows.

0(NΨ)(NΨ*)=P

Where,

N is the normalization constant.

Ψ* is the conjugate of the wavefunction.

Ψ is the wavefunction.

P is the probability.

Substitute the values in the above equation as follows.

P=0.98a1a(Ψ)(Ψ*)dx=0.98a1a(2asin2πxa)(2asin2πxa)dx=2a0.98a1a(sin2πxa)(sin2πxa)dx=2a0.98a1a(sin2πxa)2dx

The above equation is simplified as follows.

=2a0.98a1a(sin22πxa)dx=2a×[x2a8πsin4πxa]0.98a1a=2a×[(a2a8πsin4π(a)a)(0.98a2a8πsin4π(0.98a)a)]=2a×(a20.98a2a8πsin4π+a8πsin3.92π)

=2a×(a20.98a2a8πsin4π+a8πsin3.92π)=2a×(0.02a20.12869a25.12)=2a×(0.24502a50.24)=9.75×103

The plot the probabilities versus x is given in figure 1.

Physical Chemistry, Chapter 10, Problem 10.27E , additional homework tip  2

Figure 1

The plot shows the probability for the given wave function. According to this plot, the probability of finding the particle is maximum in the range of x=0.24ato0.26a and x=0.74ato0.76a which is different from the previous exercise. Also, the plot gives the curve for the sine function as given.

Conclusion

The probability for the particle having wavefunction Ψ=2asin2πxa in the range of x=0.98ato1.00a is calculated as 9.75×103.The graph of probabilities versus x is given in figure 1.

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