Concept explainers
The average value of radius in a circular system,
(a) Evaluate
See the integral table in Appendix
(b) What is the numerical value of
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
Physical Chemistry
- Normalize the wave function ψ= A sin (nπ/a x) by finding the value of the constant A when the particle is restricted to move in one dimensional box of width ‘a’.arrow_forwardFunctions of the form sin(nπx/L), where n = 1, 2, 3 …, are wavefunctions in a region of length L (between x = 0 and x = L). Show that the wavefunctions with n = 1 and 2 are orthogonal; you will find the necessary integrals in the Resource section.arrow_forwardA normalized wavefunction for a particle confined between 0 and L in the x direction is ψ = (2/L)1/2 sin(πx/L). Suppose that L = 10.0 nm. Calculate the probability that the particle is (a) between x = 4.95 nm and 5.05 nm, (b) between x = 1.95 nm and 2.05 nm, (c) between x = 9.90 nm and 10.00 nm, (d) between x = 5.00 nm and 10.00 nm.arrow_forward
- The moment of inertia of CH4 can be calculated from the expression I=8/3 mHR2 where R is the C-H bond length (109 angstrom or 109 x 1012 m). a. What is the lowest possible rotational energy of the CH4 molecule and what is the value of quantum number l associated with that rotational energy? b. Calculate the rotational energy of the molecule in the first excited state (when quantum number l = 1). c. Determine the degeneracy of the first excited state. Explain what is meant by rotational energy degeneracy.arrow_forwardConstruct the potential energy operator of a particle with potential energy V(x)=1/2kfx2, where kf is a constantarrow_forwardWhat values of J may occur in the terms (i) 1S, (ii) 2P, (iii) 3P? How many states (distinguished by the quantum number MJ) belong to each level?arrow_forward
- For 1 I have A being B, B. No, C. Yesarrow_forwardBy considering the integral ∫02π ψ*ml ψml dϕ, where ml≠m'l, confirm that wavefunctions for a particle in a ring with different values of the quantum number ml are mutually orthogonal.arrow_forwardFor a particle in a two-dimensional box with sides of equal lengths, draw rough sketches of contours of constant || for the states (a) nx=2, ny=1; (b) nx =2, ny=2. At what points in the box is || a maximum for each state?arrow_forward
- (a) For a particle in the stationary state n of a one dimensional box of length a, find the probability that the particle is in the region 0xa/4.(b) Calculate this probability for n=1,2, and 3.arrow_forwardFind an expression for the value of n of a particle of mass m in a one-dimensional box of length L such that the energy of the level is equal to the mean energy of thermal motion (1/2kT). Calculate the value of n for the case of an argon atom in a box of length 0.1 cm at 298 K.arrow_forwardEvaluate the linear momentum and kinetic energy of a free proton described by the wavefunction e−ikx with k = 5 nm−1.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY