![Pearson eText Organic Chemistry -- Instant Access (Pearson+)](https://www.bartleby.com/isbn_cover_images/9780135213711/9780135213711_largeCoverImage.gif)
Concept explainers
(a)
Interpretation:
Synthesis of (S)-1-deutrino-1-propanol should be explained.
Concept introduction:
In the nucleophilic substitution reaction, the
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
Example:
Alcohol is reaction with tosyl chloride in pyridine which provides retention of configuration of tosylated compound. This tosylated compound is further reaction with sodium methoxide which undergoes again
(b)
Interpretation:
(S)-1-deutrino-1-methoxypropane should be synthesized.
Concept introduction:
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
Example:
Alcohol is reaction with tosyl chloride in pyridine which provides retention of configuration of tosylated compound. This tosylated compound is further reaction with sodium methoxide which undergoes again
(c)
Interpretation:
(R)-1-deutrino-1-methoxypropane should be synthesized.
Concept introduction:
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
Example:
Alcohol is reaction with tosyl chloride in pyridine which provides retention of configuration of tosylated compound. This tosylated compound is further reaction with sodium methoxide which undergoes again
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 10 Solutions
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
- 1. You have an alkyl halide and the product has a thiol group without an alkyl, what is the reagant? 2. What is the reaction of disodium sulfide and Na2S, what is its product? 3. You have a thiol compound that reacts with sodium hydroxide, what do you get? 4. You have an oxyrane reacting with sulfuirc acid and methanol, what do you get? 5. Have an alkene reacting with Br, what do you get?arrow_forwardHow could you use ethylbenzene to prepare each compound? More than one step is required.arrow_forwardWhich of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A Darrow_forward
- Choose the CORRECT name for this compound. OCH3 O 2-Methoxy-5-phenyl-3-pentanone O 3-Methoxy-1-phenyl-2-butanone 4-Methoxy-1-phenyl-3-pentanone 2-Methoxy-4-phenyl-3-butanonearrow_forwardWhat product forms when the compound below is treated with Benedict's reagent? CHO H -C-OH CH,OH A) ÇH,OH H –Ç–OH CH,OH B) СНО C=0 CH,OH C) ÇOOH Н—С—ОН CH,OH D) ÇH,OH Но—ҫ—ОН CH,OH MacBook Airarrow_forwardWhat is an acceptable or preferred IUPAC name for the following compound? a. (3R,4Z)-4-methyloct-4-en-3-amine b. (3S,4Z)-4-methyloct-4-en-3-amine c. (6R,4Z)-5-methyloct-4-en-6-amine d. (6S,4Z)-5-methyloct-4-en-6-amine e. (2R,4Z)-2-(1-aminopropyl)hex-2- H2NI ene f. (2S,4Z)-2-(1-aminopropyl)hex-2-enearrow_forward
- (R-MgX) what reagent is this?arrow_forwardMatch each reagent to the product that it forms. Multiple reagents may form the same product. нох Reagent Reagents SOCI2, pyridine: C CISO2CH3, pyridine: E HCI: A PCI 3: A A) B) "It "ft "bl H₂O D) E) F) پہلے علی علیہarrow_forwardSuggest how you would convert cyclohexanol (A) to B. HO "O-H A Barrow_forward
- What compound results when 2-pentanol is treated with HCl and ZnCl2? A. CH3CH2CH2CH2CH2CL B. CH3CH(Cl)CH2CH2CH3 C. CH3CH2CH2CH2CH2ZnCl D. CH3CH2CH2Ch2CO2Clarrow_forwardDraw the product formed when pentanal (CH3 CH₂ CH₂ CH₂ CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH3OH b. [1] LiAiH4: [2] H₂O c. H₂, Pd-C d. PCC e. Na₂Cr₂O7, H₂SO4, H₂O f. Ag₂O, NH4OH g. [1] CH3 MgBr; [2] H₂O h. [1] C6H5 Li: [2] H₂O i. [1] (CH3)2 CuLi; [2] H₂O J. [1] HC=CNa; [2] H₂O k. [1] CH 3 C=CLI; [2] H₂O 1. The product in (a), then TBDMS-CI, imidazolearrow_forwardAnswer the following questions about curcumin, a yellow pigment isolated from turmeric, a tropical perennial in the ginger family and a principal ingredient in curry powder.a.In Chapter 11, we learned that most enols, compounds that contain a hydroxy group bonded to a C=C, are unstable and tautomerize to carbonyl groups. Draw the keto form of the enol of curcumin, and explain why the enol is more stable than many other enols. b.Explain why the enol O—H proton is more acidic than an alcohol O—H proton. c. Why is curcumin colored? d.Explain why curcumin is an antioxidant.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)