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Concept explainers
(a)
Interpretation:
The given compound should be synthesized from 3,3-dimethyl-l-butene.
In the nucleophilic substitution reaction, the
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
(b)
Interpretation:
The given compound should be synthesized from 3,3-dimethyl-l-butene.
Concept introduction:
Meta chloro perbenzoic acid is reaction with alkene which forms the epoxide.
Lithium aluminium hydride is used as a reducing agent.
Lithium aluminium hydride is reduced the epoxide as an alcohol which is shown below.
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Chapter 10 Solutions
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
- Arrange the compounds of each group in order of increasing boiling point. a. 1-butanol, 1-pentanol, 1-propanol b. 1,2-butanediol, 2-butanol, pentanearrow_forward7 Give the IUPAC name for the following compound. OH A. 3-methyl-1-pentenyl alcohol B. 3-vinyl-1-butanol C. 3-methyl-4-penten-1-olarrow_forwardWhich of the following compounds can react with C2H5MgBr to give 3-pentanol? a.acetone b.ethanal c.acetic acid d.ethyl formatearrow_forward
- The correct IUPAC name for this compound is: O a. 4-oxa-1-cyclohexanol O b. 4-hydroxyoxacyclohexene O c. 4-oxa-1-cyclohexenol O d. 4-oxacyclohexane-1-ol OHarrow_forwardWhat are the major products of the reaction of ethyl benzoate with hydrochloric acid and water? a. benzoic acid and ethanol b. phenylic acid and ethanol c. ethanoic acid and benzene d. acetic acid and toluene e. phenylic acid and methanolarrow_forwardWhich of the following molecules gives a condensation reaction with benzaldehyde? A. 4-methylbenzaldehyde B. 4-chlorobenzaldehyde C. 2,2-methyl propanoic acid D. 3-methylbutanoic acid E. 3-methylbenzaldehydearrow_forward
- What is the name of the major product formed during the reaction between berzoyl chloride and phenol? a. phenyl benzoate b. benzyl ester C. cyclopentanoate d. benzyl phenoate e. benzenecarboxylic acid O a O b O c earrow_forwardWhich of the following compounds is a dihydroxy alcohol? a. 2-propanol b. 1,2-ethanediol c. 1,2,3-propanetriol d. ethanol e. both 1,2-ethanediol and 1,2,3-propanetriolarrow_forward9. Assign an IUPAC name to each of the following compounds. 2. a. CH3-C-O-C-CH2-CH, b. CH3-CH2-CH-CH-C-CI L. C. CH3-CH-CH-C-Cl ČH3 CH3 d. CH3-CH-C-0-C-H Draw the structures of the esters formed by reacting the following substances 1 molecule methanol and 1 molecule phosphoric acid 2 molecules methanol and 1 molecule phosphoric acid 1 molecule methanol and 1 molecule nitric acid 1 molecule ethylene glycol and 2 molecules of nitric acid 0. A. В. C, D.arrow_forward
- 14. Draw following compounds using line formula 1-Propanethiol a. b. 2-Butanethiol C. 2-Methyl-2-butanethiol d. 1,4-Cyclohexanedithiolarrow_forward1. When an aldehyde is reduced with hydrogen (H2) gas in the presence of a transition metal catalyst, what type of product is formed? A. primary alcohol B. secondary alcohol C. tertiary alcohol D. carboxylic acidarrow_forwardWhich alkyl halide has the highest boiling point? A. CH3BrB. CH3FC. CH3ClD. CH3larrow_forward
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