(a) Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as S N 2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 1

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Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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What acetylide anion and alkyl halide are needed to synthesize each alkyne?

Complete each box using the starting material in the center. Predict the products using the reagents provided. Explain in detail with drawn out reactions please.

Draw the appropriate reagents and solvent above and or below the arrow necessary to conduct the following reactions.

Answer 2

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 3

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 4

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 5

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 6

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 7

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 8

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 9

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 10

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 11

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Draw structures for the three alkynes having...Ch. 11 - Prob. 11.2P Ch. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Prob. 11.9P Ch. 11 - Problem 11.9 Draw the products formed when is...

Solution Summary: The author explains that the acetylide anion and alkyl halide that are used to prepare the given Alkyne are to be predicted.

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Chapter 11 Solutions