The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted. Concept introduction: The electrophilic addition of H + to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C + carbon atom to form a neutral product. The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C + from the front (wedge) or from behind (dash). This leads to two different products.

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Answer 1

Question

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

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Answer 2

Question

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

Expert Solution & Answer

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See solution

Answer 3

Question

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

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Answer 4

Question

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

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Answer 5

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

Answer 6

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

Answer 7

Chapter 11, Problem 11.29P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the addition of HCl to dihydropyran is to be drawn, and the major product is to be predicted.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces carbocation intermediate. The more stable carbocation proceeds to the next coordination step. In the next step, the nucleophile attacks the positively charged C+ carbon atom to form a neutral product.

The carbocation intermediate is a trigonal planar, and the nucleophile can attack the C+ from the front (wedge) or from behind (dash). This leads to two different products.

Answer 8

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Answer 9

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Answer 11

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

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