ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
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Chapter 11, Problem 11.7YT
Interpretation Introduction

Interpretation:

The hypothetical two-step mechanism in which water adds across the double bond in equation 11-13 according to the mechanism in equation 11-3 is to be drawn. The OH- intermediate is to be identified. This mechanism is unfeasible whereas the same mechanism with HCl as the acid is feasible; the reason behind this is to be determined.

Concept introduction:

Electron rich compounds of hydrogen contain excess valence electrons to form covalent bonds. Electron-poor (electrophiles) substrates can accept an electron pair to form a new bond. They are attached by nucleophiles (electron rich). In alkene, the strong Bronsted acids such as HCl, HBr, HI, and H2SO4 quickly add to the C=C functional group. The hydrogen and conjugate base of the acid forms covalent bond with the alkene molecule.

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ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5

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