(a) Interpretation: The reaction that has greater standard entropy of activation is to be stated. Concept introduction: The standard entropy of activation is represented by the symbol Δ S ° ⊥ . It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of Δ S ° ⊥ increases the rate of reaction . A negative value of Δ S ° ⊥ decreases the rate of reaction as the entropy decreases.

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Answer 1

Question

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

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Refer to the reaction energy diagram to answer parts (a) through (e). (a) What is the rate-limiting STEP? (Select from 1, 2, 3, or 4) (b) The TRANSITION STATE for the fastest step is: (c) In the 3rd step which INTERMEDIATE structurally resembles the transition state according to the Hammon postulate? (d) Which STEP NUMBER is endergonic? (e) The number of intermediates in the overall reaction is:

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Kindly answer only item no. 13.12 (a) & (b). Thank you.

Answer 2

Question

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

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Answer 3

Question

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

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Answer 4

Question

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

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Answer 5

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Answer 6

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Answer 7

Chapter 11, Problem 11.34P

Interpretation Introduction

(a)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction that has greater standard entropy of activation is to be stated.

Concept introduction:

The standard entropy of activation is represented by the symbol ΔS°⊥. It is an intrinsic property, that is, it is independent of mass. It depends on temperature. A positive value of ΔS°⊥ increases the rate of reaction. A negative value of ΔS°⊥ decreases the rate of reaction as the entropy decreases.

Answer 10

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Answer 11

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Answer 13

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains that the formation of product A has greater standard entropy of activation.

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