(a)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into
The combination of
(b)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(c)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(d)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(e)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(f)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(g)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(h)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols or aldehyde into carboxylic acid through oxidation reaction.
The combination of
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Chapter 11 Solutions
Organic Chemistry (9th Edition)
- Write the reaction involved in Ferrox Test. a. What is the species responsible? b. Why is phenol negative in Ferrox Test? Based on the theoretical result, what is the order of reactivity of primary, secondary, and tertiary alcohols in the Lucas Test? a. Lucas Reagent contains ZnCl2 in HCl. What is the role of ZnCl2? What reagents are used in the esterification of Alcohols and Phenols? a. Write the reaction involved in Primary Alcohol (Ethanol) and Acetyl Chloride b. Write the reaction involved in Phenol and Acetyl Chloride What is the purpose of the Chromic acid test? a. What are the reagents used? b. Write oxidation reaction of Primary Alcohols and Secondary Alcoholsarrow_forwardMeasure the weight of acetylsalicylic in aspirin. note: % of acetylsalicylic acid in aspirin is 5% provide a good expliationarrow_forward.771g of acetominophen reacts with 1.0 eqivalent of 1.5M KOH and 1.2 equivalents of pure liquid n-butyl bromide in ethanol solvent to give .901g of the willimason ether product a) calculate the volume of the base and the volume of the SN2 electrophile needed for the reaction needed for the reaction using the equivalents given above b) caclulate the percent yield of the reactionarrow_forward
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- Kiko, a Chem 31.1 student, accidentally shuffled two test tubes with different compounds on his way to the laboratory. To confirm the possible identities of the compounds, Kiko added neutral KMnO4 and Lucas reagents to both test tubes labeled A and B. Test tube A gave a brown precipitate in neutral KMnO4 while test tube B produced a purple solution in the same test. Upon subjecting to Lucas Test, both test tubes produced layers. Which of the following are the possible identities of the compounds A and B? a. Sec-butanol and 3-methyl-3-pentanol b. n-propanol and tert-butanol c. isopropyl alcohol and 4-nitrophenol d. hexanol and cyclopentanolarrow_forwarda) From this flow chart, which acid is extracted when sodium bicarbonate is used as an extraction solvent? Explain, use knowledge of pKa, why this acid is extracted as opposed to the other acid present. b) What would be the end results if you first extract with NaOH, and then with NaHCO3? c) What would be the results after the addition of HCl to the NaOH extract and the NaHCO3 extracts?arrow_forward1. What type of reaction explains solubility of phenol in sodium hydroxide? Explain the organic product formed. 2. How do the reactions of phenol samples with FeCl3 compare? Which structural component of the phenols account for the observationarrow_forward
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EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT