a) Interpretation: The more reactive nucleophile among the following pairs (CH 3 ) 2 N - or (CH 3 ) 2 NH Concept introduction: The major factor which affects the S N 2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Question

When a single compound contains both a nucleophile and a leaving group, an intramolecular reaction occurs. With this in mind, what is the structure and stereochemistry of the following reaction?

Answer 1

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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When a single compound contains both a nucleophile and a leaving group, an intramolecular reaction occurs. With this in mind, what is the structure and stereochemistry of the following reaction?

For each of the following statements, indicate if they apply to SN1 reactions, SN2 reactions, or both. (a) involve a nucleophile in the rate determining step _______________________ (b) enhanced by use of strong nucleophiles _______________________ (c) carbocation intermediate _________________________ (d) inversion of configuration ___________________________

Which of the following compounds (A or M) would be the better choice for a nucleophilic substitution reactionusing Compound T as the starting material and DMSO as the solvent? Would the resulting reaction be SN1 or SN2?

Answer 2

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 3

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 4

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 5

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 6

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 7

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 8

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 9

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 10

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 11

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 12

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Ch. 11.1 - Prob. 1P Ch. 11.2 - Prob. 2P Ch. 11.2 - Prob. 3P Ch. 11.3 - Prob. 4P Ch. 11.3 - Prob. 5P Ch. 11.3 - Rank the following compounds in order of their...Ch. 11.3 - Organic solvents like benzene, ether, and...Ch. 11.4 - Prob. 8P Ch. 11.4 - Prob. 9P Ch. 11.4 - Prob. 10P

Chapter 11 Solutions