Chemistry (Looseleaf) - With Student Solutions Manual
3rd Edition
ISBN: 9780077822828
Author: Burdge
Publisher: MCG
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Textbook Question
Chapter 11.5, Problem 1PPC
Practice ProblemCONCEPTUALIZE
Referring to the cesium chloride structure in Figure 11.26(a), determine the density of a hypothetical ionic compound with the same unit cell, given that the radii of the anions and cations are 150 pm and 92 pm, respectively: and that their average masses are 98 amu and 192 amu, respectively.
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onlyroundoffat 2decimalplaces in final answer tyIron has an atomic weight of 55.85 g/mol and a density of 7.86 g/cm3. It crystallizes in a cubic unit cell with an edge length of 0.46 nm. How many atoms are in the cell?
Answer all 3 parts (A, B, & C).
All noble gases except helium crystallize with cubic close-packed structures at very low temperatures. Cubic close-packed structures have face-centered cubic unit cells. Xenon freezes at 161.40 K.
A) What is the coordination number of xenon in the solid-state?
B) Of the following: Covalent bonding, Ionic bonding, dispersion forces, ion-dipole forces, dipole-dipole forces, what holds the xenon atoms in place in the solid-state?
C) Xe has a density of 3.640 g/cm^3, what is the approximate radius of a xenon atom?
The ionic compound, CsI, forms a body centered cubic structure (see below) where the anions occupy the corners of the crystal (red) and the cations the body centered position (green). If the density of the compound is 4.51 g/cm^3 and the ionic radius of Cs + is 169 pm, what is the ionic radius of I − in pm?
Key Concept: The atoms are touching the diagonal in the center of the cube. This makes it equal to the sum of 2 times the radius of each atom.
Strategy: Determine the length of the diagonal,d, and recall that the length of the side, l, is given by l = d/3 0.5. This is a result of the use of the Pythagorean theorem relating the length of the side to d.With the length of the side you can determine the volume of the unit cell.From the number of atoms in the unit cell determine the mass of the unit cell.Use these to get the density.
Chapter 11 Solutions
Chemistry (Looseleaf) - With Student Solutions Manual
Ch. 11.1 - Prob. 1PPACh. 11.1 - Prob. 1PPBCh. 11.1 - Prob. 1PPCCh. 11.1 - Prob. 1CPCh. 11.1 - Prob. 2CPCh. 11.2 - Prob. 1PPACh. 11.2 - Prob. 1PPBCh. 11.2 - Prob. 1PPCCh. 11.2 - Prob. 1CPCh. 11.2 - 11.2.2 Given the following information for ...
Ch. 11.2 - 11.2.3 Using the graph, estimate the vapor...Ch. 11.2 - Using the result from question 11.2.3 and another...Ch. 11.3 - Practice ProblemATTEMPT When silver crystallizes,...Ch. 11.3 - Practice Problem BUILD
The density of sodium metal...Ch. 11.3 - Practice Problem CONCEPTUALIZE The diagram shows...Ch. 11.3 - 11.3.1 Nickel has a face-centered cubic unit cell...Ch. 11.3 - Prob. 2CPCh. 11.4 - Prob. 1PPACh. 11.4 - Prob. 1PPBCh. 11.4 - Prob. 1PPCCh. 11.5 - Practice ProblemATTEMPT LiF has the same unit cell...Ch. 11.5 - Practice ProblemBUILD NiO also adopts the...Ch. 11.5 - Practice ProblemCONCEPTUALIZE Referring to the...Ch. 11.6 - Practice Problem ATTEMPT
Aluminum metal...Ch. 11.6 - Practice Problem BUILD
Copper crystallizes in a...Ch. 11.6 - Prob. 1PPCCh. 11.6 - 11.6.1 How much energy (in kJ) is required to...Ch. 11.6 - 11.6.2 How much energy (in kJ) is given off when...Ch. 11.7 - Practice ProblemATTEMPT Calculate the amount of...Ch. 11.7 - Practice ProblemBUILD Determine the final state...Ch. 11.7 - Prob. 1PPCCh. 11.7 - Prob. 1CPCh. 11.7 - Prob. 2CPCh. 11.8 - Prob. 1PPACh. 11.8 - Practice Problem BUILD
Sketch the phase diagram of...Ch. 11.8 - Prob. 1PPCCh. 11 - Which of the following would you expect to be more...Ch. 11 - 11.2
Which of the following would you expect to be...Ch. 11 - Prob. 3KSPCh. 11 - Prob. 4KSPCh. 11 - Give an example for each type of intermolecular...Ch. 11 - 11.2 Explain the term polarizability. What kind of...Ch. 11 - Prob. 3QPCh. 11 - Prob. 4QPCh. 11 - 11.5 What physical properties are determined by...Ch. 11 - Prob. 6QPCh. 11 - Describe the types of intermolecular forces that...Ch. 11 - Prob. 8QPCh. 11 - Prob. 9QPCh. 11 - The binary hydrogen compounds of the Group 4A...Ch. 11 - 11.11 List the types of intermolecular forces that...Ch. 11 - Prob. 12QPCh. 11 - Prob. 13QPCh. 11 - Arrange the following in order of increasing...Ch. 11 - Diethyl ether has a boiling point of 34 .5°C , and...Ch. 11 - 11.16 Which member of each of the following pairs...Ch. 11 - Prob. 17QPCh. 11 - Explain in terms of intermolecular forces why (a)...Ch. 11 - What kind of attractive forces must be overcome to...Ch. 11 - Prob. 20QPCh. 11 - Prob. 21QPCh. 11 - Explain why liquids, unlike gases, are virtually...Ch. 11 - 11.23 What is surface tension? What is the...Ch. 11 - Prob. 24QPCh. 11 - Prob. 25QPCh. 11 - 11.26 A glass can be filled slightly above the rim...Ch. 11 - 11.27 Draw diagrams showing the capillary action...Ch. 11 - Prob. 28QPCh. 11 - Why does the viscosity of a liquid decrease with...Ch. 11 - Why is ice less dense than water?Ch. 11 - 11.31 Outdoor water pipes have to be drained or...Ch. 11 - Prob. 32QPCh. 11 - Prob. 33QPCh. 11 - Prob. 34QPCh. 11 - Predict the viscosity of ethylene glycol relative...Ch. 11 - 11.36 Vapor pressure measurements at several...Ch. 11 - The vapor pressure of liquid X is lower than that...Ch. 11 - 11.38 Define the following terms: crystalline...Ch. 11 - Describe the geometries of the following cubic...Ch. 11 - Classify the solid states in terms of crystal...Ch. 11 - The melting points of the oxides of the...Ch. 11 - Define X-ray diffraction. What are the typical...Ch. 11 - 11.43 Write the Bragg equation. Define every term...Ch. 11 - 11.44 What is the coordination number of each...Ch. 11 - Calculate the number of spheres that would be...Ch. 11 - Metallic iron crystallizes in a cubic lattice. The...Ch. 11 - Barium metal crystallizes in a body-centered cubic...Ch. 11 - 11.48 Vanadium crystallizes in a body-centered...Ch. 11 - Europium crystallizes in a body-centered cubic...Ch. 11 - 11.50 Crystalline silicon has a cubic structure....Ch. 11 - 11.51 A face-centered cubic cell contains 8 X...Ch. 11 - When X rays of wavelength 0.090 nm are diffracted...Ch. 11 - The distance between layers in an NaCl crystal is...Ch. 11 - Identify the unit cell of molecular iodine ( I 2 )...Ch. 11 - Shown here is a zinc oxide unit cell. What is the...Ch. 11 - Prob. 56QPCh. 11 - Prob. 57QPCh. 11 - A solid is hard, brittle, and electrically...Ch. 11 - A solid is soft and has a low melting point (below...Ch. 11 - Prob. 60QPCh. 11 - 11.61 Which of the following are molecular solids...Ch. 11 - Classify the solid state of the following...Ch. 11 - Prob. 63QPCh. 11 - Prob. 64QPCh. 11 - Define glass. What is the chief component of...Ch. 11 - 11.66 What is a phase change? Name all possible...Ch. 11 - What is the equilibrium vapor pressure of a...Ch. 11 - Use any one of the phase changes to explain what...Ch. 11 - 11.69 Define the following terms: (a) molar heat...Ch. 11 - How is the molar heat of sublimation related to...Ch. 11 - What can we learn about the intermolecular forces...Ch. 11 - The greater the molar heat of vaporization of a...Ch. 11 - Prob. 73QPCh. 11 - As a liquid is heated at constant pressure, its...Ch. 11 - What is critical temperature? What is the...Ch. 11 - Prob. 76QPCh. 11 - 11.77 How do the boiling points and melting points...Ch. 11 - Prob. 78QPCh. 11 - The vapor pressure of a liquid in a closed...Ch. 11 - Wet clothes dry more quickly on a hot, dry day...Ch. 11 - Which of the following phase transitions gives off...Ch. 11 - 11.82 A beaker of water is heated to boiling by a...Ch. 11 - Prob. 83QPCh. 11 - Calculate the amount of heat (in kJ) required to...Ch. 11 - Prob. 85QPCh. 11 - The molar heats of fusion and sublimation of...Ch. 11 - How is the rate of evaporation of a liquid...Ch. 11 - 11.88 The following compounds, listed with their...Ch. 11 - Prob. 89QPCh. 11 - A student hangs wet clothes outdoors on a winter...Ch. 11 - Explain why steam at 100°C causes more serious...Ch. 11 - What is a phase diagram? What useful information...Ch. 11 - 11.93 Explain how water’s phase diagram differs...Ch. 11 - The blades of ice skates are quite thin, so the...Ch. 11 - 11.95 A length of wire is placed on top of a block...Ch. 11 - Prob. 96QPCh. 11 - Prob. 97QPCh. 11 - 11.98 Name the kinds of attractive forces that...Ch. 11 - Prob. 99APCh. 11 - At –35°C , liquid HI has a higher vapor pressure...Ch. 11 - Prob. 101APCh. 11 - Prob. 102APCh. 11 - Prob. 103APCh. 11 - Prob. 104APCh. 11 - Prob. 105APCh. 11 - A CO 2 fire extinguisher is located on the outside...Ch. 11 - Prob. 107APCh. 11 - A flask of water is connected to a powerful vacuum...Ch. 11 - Prob. 109APCh. 11 - The interionic distances of several alkali halide...Ch. 11 - Which has a greater density, crystalline Si O 2 or...Ch. 11 - A student is given four solid samples labeled W,...Ch. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - X rays of wavelength 0.154 nm strike an aluminum...Ch. 11 - 11.116 The properties of gases, liquids, and...Ch. 11 - Prob. 117APCh. 11 - Prob. 118APCh. 11 - Prob. 119APCh. 11 - Prob. 120APCh. 11 - Prob. 121APCh. 11 - 11.122 The distance between and is 257 pm in...Ch. 11 - Prob. 123APCh. 11 - Prob. 124APCh. 11 - 11.125 Calculate the for the following processes...Ch. 11 - 11.126 Which liquid would you expect to have a...Ch. 11 - 11.127 A beaker of water is placed in a closed...Ch. 11 - Prob. 128APCh. 11 - Prob. 129APCh. 11 - Carbon and silicon belong to Group 4A of the...Ch. 11 - Prob. 131APCh. 11 - Prob. 132APCh. 11 - Prob. 133APCh. 11 - Prob. 134APCh. 11 - Prob. 135APCh. 11 - Prob. 136APCh. 11 - Prob. 137APCh. 11 - Prob. 138APCh. 11 - Prob. 139APCh. 11 - 11.140 Sketch the cooling curves of water from...Ch. 11 - Prob. 141APCh. 11 - Prob. 142APCh. 11 - A closed vessel of volume 9.6 L contains 2.0 g of...Ch. 11 - 11.144 The electrical conductance of copper metal...Ch. 11 - 11.145 Assuming ideal behavior, calculate the...Ch. 11 - Explain why drivers are advised to use motor oil...Ch. 11 - Which of the following compounds is most likely to...Ch. 11 - 11.148 A chemistry instructor performed the...Ch. 11 - Prob. 149APCh. 11 - Prob. 150APCh. 11 - The phase diagram of helium is shown. Helium is...Ch. 11 - 11.152 The phase diagram of sulfur is shown. (a)...Ch. 11 - Prob. 153APCh. 11 - Prob. 154APCh. 11 - Prob. 155APCh. 11 - Prob. 156APCh. 11 - Prob. 157APCh. 11 - Prob. 158APCh. 11 - 11.159 Why do citrus growers spray their trees...Ch. 11 - Prob. 2SEPPCh. 11 - 3. Each cubic unit cell (edge length a = 543 pm)...
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