EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 13, Problem 13.16P
Interpretation Introduction

(a)

Interpretation:

The structure of the molecule C3H7Br is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule C2H3Cl3 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule C5H8Br4 is to be stated.

Concept introduction:

Nuclear magnetic resonance is a type of spectroscopy in which number of different kind of protons present in different environment can be detected. The NMR spectra of any molecule can easily interpreted if structure of a molecule is known. In the NMR spectra, sometimes one absorption peak is splitted into two or more peaks. This is due to the spin of neighboring proton which affects the total magnetic field experienced by an observed proton.

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1 (a) In the following reactions, CI (1) LIAIH, A (2) H20 MCPBA (i) Draw the structure of compounds A and B. (ii) For each reaction, explain the type of reaction involved. (iii) Explain the successful transformation of compound A using mass spectra. (b) Complete the following reactions by filling in missing reactants or product. (i) (1) O3 (2) CH;SCH3 (ii) он (CH3)3(COOH) D Ti(OCH(CH3)2l4 (-)-DET
Cyclohex-2-enone has two protons on its carbon-carbon double bond (labeled Ha and Hb) and two protons on the carbon adjacent to the double bond (labeled Hc). (a) If Jab = 11 Hz and Jbc = 4 Hz, sketch the splitting pattern observed for each proton on the sp2 hybridized carbons. (b) Despite the fact that Ha is located adjacent to an electron-withdrawing C=O, its absorption occurs upfield from the signal due to Hb (6.0 vs. 7.0 ppm). Offer an explanation.
(1) (ii) (iii) (iv) (v) What is the relationship between the compounds [Cl-Ag-SCN]™ and [SCN-Ag-CIJ? Name the compounds whose molecular formulae are given in Question 1(a) (i). Which of the compounds, [Cl-Ag-SCN] and [SCN-Ag-CI], is the more stable? Explain your answer. Draw the boundary surfaces of all 3d orbitals and label these orbitals according to the conventional nomenclature. Clearly draw and label the Cartesian axes. Draw the crystal field splitting diagram for a linear compound, e.g. [Cl-Ag-SCN] or [SCN-Ag-CI], aligned along the z-axis. You only need to indicate the order of the individual d orbitals as a function of the energy. Explain your answer.
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