(a) Interpretation: The number of lines expected in the proton NMR of + NH 4 is to be stated. The intensity of each line is to be stated. Concept introduction: Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Question

Want to see the full answer?

Answer 1

Question

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

What is the resonance frequency of an 11B nucleus in a 2.35 T magnetic field (g= 8.584 x 107 rad T-1 s-1)?

We calculated that the resonance frequency of an 1H in the presence of an 11.74 tesla magnet was 500MHz, and we later saw that a 13C nucleus resonantes at approximately 125 MHz in this same magnetic field. What is the resonance frequency of a 19F nucleus in the presence of an 11.74 tesla magnet?

According to the shell model, the spin-parity of the ground state of 0-18 (Z=8, A=15) nucleus is: O Nuclear spin: 1, parity: + Nuclear spin: 0, parity: + Nuclear spin: 2 parity: + Nuclear spin: 2 parity: - Ο Ο Ο Ο 13

Answer 2

Question

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 6

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 7

Chapter 13, Problem 13.50AP

Interpretation Introduction

(a)

Interpretation:

The number of lines expected in the proton NMR of +NH4 is to be stated. The intensity of each line is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The number of lines expected in the 13C NMR of CDCl3 is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 10

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 11

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the samples of the compounds H2CD−I, D2CH−I, and D3C−I can be distinguished from each other by proton NMR spectrum is to be stated. The other technique that can be used is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Solution Summary: The author states the number of lines expected in the proton NMR and the intensity of each line.

Concept explainers

Videos

Want to see the full answer?

Chapter 13 Solutions