ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
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Question
Chapter 13, Problem 13.2YT
Interpretation Introduction
Interpretation:
The synthetic step shown is to be completed showing water as the solvent and to show that the reaction is carried out at
Concept introduction:
A synthetic step is written with just the overall reactants, the added reagents, the reaction conditions, and the overall products. The details of how the reactants and reagents react are not included. The reaction conditions may include the solvent, any catalysts (acid/base) used, and the temperature. The reaction conditions, including the solvent, are shown below the reaction arrow.
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Write the mechanism of the following reaction.
In the workup of the grignard reaction of turning bromobenzene to benzoic acid, we start by mixing the grignard with HCl and diethyl ether. We discard the aqueous layer and wash the organic layer with water. Then, the organic layer is extracted with NaOH. Then, the extracts are heated to remove ether. Then, it is precipitated with HCl. Precipitate collected. Let it dry and finally, purified with toluene and hexanes.
Please make a flowchart of the process of this workup indicating what products and byproducts are forming. And what compounds are in the aqueous layer and organic layer in the steps.
Provide an arrow pushing mechanism for these reactions.
Chapter 13 Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
Ch. 13 - Prob. 13.1PCh. 13 - Prob. 13.2PCh. 13 - Prob. 13.3PCh. 13 - Prob. 13.4PCh. 13 - Prob. 13.5PCh. 13 - Prob. 13.6PCh. 13 - Prob. 13.7PCh. 13 - Prob. 13.8PCh. 13 - Prob. 13.9PCh. 13 - Prob. 13.10P
Ch. 13 - Prob. 13.11PCh. 13 - Prob. 13.12PCh. 13 - Prob. 13.13PCh. 13 - Prob. 13.14PCh. 13 - Prob. 13.15PCh. 13 - Prob. 13.16PCh. 13 - Prob. 13.17PCh. 13 - Prob. 13.18PCh. 13 - Prob. 13.19PCh. 13 - Prob. 13.20PCh. 13 - Prob. 13.21PCh. 13 - Prob. 13.22PCh. 13 - Prob. 13.23PCh. 13 - Prob. 13.24PCh. 13 - Prob. 13.25PCh. 13 - Prob. 13.26PCh. 13 - Prob. 13.27PCh. 13 - Prob. 13.28PCh. 13 - Prob. 13.29PCh. 13 - Prob. 13.30PCh. 13 - Prob. 13.31PCh. 13 - Prob. 13.32PCh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Prob. 13.36PCh. 13 - Prob. 13.37PCh. 13 - Prob. 13.38PCh. 13 - Prob. 13.39PCh. 13 - Prob. 13.40PCh. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Prob. 13.43PCh. 13 - Prob. 13.44PCh. 13 - Prob. 13.45PCh. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Prob. 13.50PCh. 13 - Prob. 13.51PCh. 13 - Prob. 13.1YTCh. 13 - Prob. 13.2YTCh. 13 - Prob. 13.3YTCh. 13 - Prob. 13.4YTCh. 13 - Prob. 13.5YTCh. 13 - Prob. 13.6YTCh. 13 - Prob. 13.7YTCh. 13 - Prob. 13.8YTCh. 13 - Prob. 13.9YTCh. 13 - Prob. 13.10YTCh. 13 - Prob. 13.11YTCh. 13 - Prob. 13.12YT
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