The α hydrogen of N , N -disubstituted amide is less acidic than α hydrogen of an ester has to be explained. Concept introduction: Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

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Answer 1

Question

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

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Answer 2

Question

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

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Answer 3

Question

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

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Answer 4

Question

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

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Answer 5

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

Answer 6

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

Answer 7

Chapter 13, Problem 26P

Interpretation Introduction

Interpretation:

The α hydrogen of N,N-disubstituted amide is less acidic than α hydrogen of an ester has to be explained.

Concept introduction:

Acidity of α hydrogen that is abstracted by a base depends on the stability of the conjugate base. If the negative charge on conjugate base is stabilized by resonance or delocalization of electrons, then the loss of α hydrogen becomes favorable. More stable the conjugate base, more acidic is the α hydrogen atom.

Answer 8

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Answer 9

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Answer 11

Ch. 13.1 - Identify the most acidic hydrogen in each...Ch. 13.1 - Prob. 2P Ch. 13.1 - Prob. 3P Ch. 13.1 - Prob. 4P Ch. 13.1 - Explain why HO cannot remove a proton from the...Ch. 13.2 - Prob. 6P Ch. 13.2 - Prob. 7P Ch. 13.3 - Prob. 8P Ch. 13.3 - Prob. 9P Ch. 13.3 - Prob. 10P

Solution Summary: The author explains that the acidity of hydrogen that is abstracted by a base depends on the stability of the conjugate base.

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