Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 13, Problem 29P
(a)
Interpretation Introduction
Interpretation:
Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.
Concept introduction:
Aldol reaction is an addition reaction of
Mechanism for the aldol addition:
(b)
Interpretation Introduction
Interpretation:
Aldehyde or ketone that is obtained when the given compound is heated in basic aqueous solution to be identified.
Concept introduction:
Aldol reaction is an addition reaction of aldehydes and ketones.
Mechanism for the aldol addition:
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What aldehyde or ketone would be obtained when each of the following compounds is heated in a basic aqueous solution? a. 2-ethyl-3-hydroxyhexanal c. 2,4-dicyclohexyl-3-hydroxybutanal b. 4-hydroxy-4-methyl-2-pentanone d. 5-ethyl-5-hydroxy-4-methyl-3-heptanone
4-Hydroxy- and 5-hydroxyaldehydes exist primarily as cyclic hemiacetals. Draw the structure of the cyclic hemiacetal formed by each of the following: a. 4-hydroxybutanal b. 4-hydroxypentanal c. 5-hydroxypentanal d. 4-hydroxyheptanal
Give the appropriate/simplest IUPAC name of the compound (see the attached picture)
A.) 5-tert-butyl-2-methylcyclopentanone
B.) 2-tert-butyl-5-methylcyclopentanone
C.) 2-tertbutyl-5-methylcyclopentanone
D.) 2-methyl-5-tertbutylcyclopentanone
E.) 5-methyl-2-tertbutylcyclopentanone
Chapter 13 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 13.1 - Identify the most acidic hydrogen in each...Ch. 13.1 - Prob. 2PCh. 13.1 - Prob. 3PCh. 13.1 - Prob. 4PCh. 13.1 - Explain why HO cannot remove a proton from the...Ch. 13.2 - Prob. 6PCh. 13.2 - Prob. 7PCh. 13.3 - Prob. 8PCh. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.4 - Prob. 11PCh. 13.5 - Prob. 12PCh. 13.5 - Prob. 13PCh. 13.6 - Prob. 14PCh. 13.7 - Prob. 16PCh. 13.8 - Prob. 17PCh. 13.8 - Prob. 18PCh. 13.8 - Prob. 19PCh. 13.9 - Prob. 20PCh. 13.10 - Propose a mechanism for the formation of...Ch. 13.10 - Prob. 22PCh. 13.10 - a. If the biosynthesis of palmitic acid were...Ch. 13 - Draw the enol tautomers for each of the following...Ch. 13 - Number the following compounds in order from...Ch. 13 - Prob. 26PCh. 13 - Explain why the pKa of a hydrogen bonded to the...Ch. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Using cyclopentanone as the reactant, show the...Ch. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Prob. 44PCh. 13 - Describe how the following compounds can be...Ch. 13 - Prob. 46PCh. 13 - Which would require a higher temperature:...Ch. 13 - Prob. 48PCh. 13 - Propose a mechanism for the following reaction:Ch. 13 - Show how the following compounds could be...Ch. 13 - Prob. 51PCh. 13 - Prob. 52P
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