Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 13, Problem 6PP
Interpretation Introduction

Interpretation:

Amongst the compounds in section 13.5 (given in the textbook), conjugated dienes, isolate diene and isolated enyne are to be identified.

Concept introduction:

Conjugated dienes are the organic compounds that contains alternate double bonds along the chain.

When one or more saturated carbon atoms intervene between the double bonds of an alkadiene, the double bonds are said to be isolated.

Alkenyne is a hydrocarbon with a double and triple bond. In isolated enyne, one or more saturated carbon atoms intervene between the double and triple bonds of an alkaenyne, the double bonds are said to be isolated.

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Explain why :(a) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.(b) Alkyl halides, though polar, are immiscible with water.
Give reasons: (i) C—Cl bond length in chlorobenzene is shorter than C—Cl bond length in CH3—Cl.(ii) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.(iii) SN1 reactions are accompanied by racemization in optically active alkyl halides
(a) Explain how pyrrole is isoelectronic with the cyclopentadienyl anion.(b) Specifically, what is the difference between the cyclopentadienyl anion and pyrrole?(c) Draw resonance forms to show the charge distribution on the pyrrole structure.

Chapter 13 Solutions

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