(a) Interpretation: Whether CO would have pure vibrational spectra or not is to be stated. Concept introduction: Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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Answer 1

Question

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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Students have asked these similar questions

The vibrations of a CO2 molecule are symmetrical stretch, bend, and asymmetrical stretch (Figure ), with frequencies of 4.02x1013 s-1, 2.00x1013 s-1, and 7.05x1013 s-1, respectively. (a) What wavelengths correspond to these vibrations? (b) Calculate the energy (in J) of each vibration. Which uses the least energy?

(A) Explain why the spacings between the bands in the vibrational spectrum of a diatomic molecule would be expected to decrease with increasing vibrational quantum number. (B) Explain why a molecule with no dipole moment is microwave inactive but may show an infrared spectrum. (C) Explain the occurrence of P and R branches in the rotational fine structure of a vibrational transition of a diatomic molecule such as HCl or CO.

Rotational spectra are affected slightly by the fact that different isotopes have different masses. Suppose a sample of the common isotope 1H35Cl is changed to 1H37Cl. (a) By what fraction is the molecule’s rotational inertia different? (The bond length is 0.127 nm in each case.) (b) What is the change in energy of theℓ = 1 to theℓ = 0 transition if the isotope is changed?

Answer 2

Question

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Expert Solution & Answer

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Answer 3

Question

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 6

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 7

Chapter 14, Problem 14.59E

Interpretation Introduction

(a)

Interpretation:

Whether CO would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether He would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether SO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether SO3 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains that vibrational spectroscopy is observed due to vibration of accompanied in a molecule.

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Chapter 14 Solutions