(a)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
(b)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
(c)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
(d)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
(e)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
(f)
Interpretation:
The individual symmetry element for the
Concept introduction:
Proper rotation is when rotation occurs through the axis of rotation. It is done by rotating the molecule through
Improper rotation is when rotation occurs through the axis of rotation as well as reflection in a plane which is perpendicular to the axis of rotation.
Proper rotations are
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Chapter 14 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
- B) Identify all the elements of symmetry of IrCl(CO) [P(C6H5)3]2 and the point group assignment. PPH3 B CI- C=O Ph3Parrow_forward(c) Using POC13 as an example, develop the reducible representation of its point group.arrow_forwardFor the point group D3h, confirm that the irreducible representation E′ is orthogonal (in the sense defined by eqn 10B.7) to the irreducible representations A′1, A′2 , and E″.arrow_forward
- A symmetry group of order h = 8 is known to have five (5) classes. Three of its irreducible representations have a dimensionality of 1. Based on this, what are the dimensions of its remaining irreducible representation(s)? 1, 1, 1 1, 2 1, 1, 1, 1, 1 2,2 1, 2, 2 OOOarrow_forwardConsider the octahedral species CrCl63- (point group Oh). What point group results by (a) removing one Cl (b) replacing one Cl with one Br (c) removing two trans Cl’sarrow_forwardWhat is the difference between the symmetry operators and point groups of NF3 and NF2CI?arrow_forward
- Using the relationships imposed by the orthogonality theorem, predict the characters, XK(R), that have been omitted from this table, and match each with its correct value. All symmetry elements and irreducible representations (labelled with subscripts k = 1, 2, 3, 4, and 5) are included in this table. + X2(C3) ◆ X3(C₂) + X4(0d) X5(E) - ₁₁ [₂ [3 T4 [5 E 1 3 1 3 _?___ 6 S4 8 C3 1 1 1 -1 T -1 0 ? 1 0 -1 A. 1 B.-2 C. 2 D.-1 E. 3 F. 0 3 C₂ 1 -1 ? 어 -1 2 60d 1 -1 -1 ? Oarrow_forwardLet A and B be Boolean algebras and f : A → B is an isomorphism, and A is atomic. (a) B is atomic, (b) B is complete (c) A is atomless (d) B is atomlessarrow_forwardThe C3 point group has symmetry elements E, C3, σv, σ and ov" - True False the number of classes in this point group is 5.arrow_forward
- What is the point group of the molecule SOF4 (S is the central atom)?arrow_forward5. (a) Deduce the point group of the follo species : OH (i) HO HO, (ü) Co4(Cp)4 (iüi) PF3CI2 (one Cl axial and one Cl equatorial)arrow_forwardDraw the shape of the [XeFs] ion and answer the questions below: (i) List the symmetry elements and the symmetry operations of the [XEF5] ion. (ii) What is the point group of the [XeF5] ion? What is the order of the point group of the [XeFs] ion? (iii) Using the [XeF5] as an example, show that C" = E.arrow_forward
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