Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 14, Problem 14.86E
Dioctyl sulfide,
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问题3
The 14 N160 molecule undergoes a transition between its rotational ground state and its
rotational first excited state. Approximating the diatomic molecule as a rigid rotor, and given
that the bond length of NO is 1.152 Angstroms, calculate the energy of the transition. As your
final answer, calculate the temperature T in Kelvin, such that Eshermal = kBT equals the
energy of the transition between NO's rotational ground state and first excited state.
A microwave using 18.99cm IR radiation is used to heat 18.2g water from 18.8C to 71.2C. Find the number of MOLES of photons required to accomplish this task.
2. Molecules absorb IR radiation consistent with vibrational energy and rotational energy. Which of these is
present in condensed phases (liquid, solution, solid)?
Chapter 14 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
Ch. 14 - Prob. 14.1ECh. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8ECh. 14 - Prob. 14.9ECh. 14 - Prob. 14.10E
Ch. 14 - Prob. 14.11ECh. 14 - Prob. 14.12ECh. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Diatomic sulfur, S2, was detected in the tail of...Ch. 14 - Prob. 14.16ECh. 14 - Prob. 14.17ECh. 14 - Prob. 14.18ECh. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Which of the following molecules should have pure...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - Derive equation 14.21 from the E expression...Ch. 14 - Prob. 14.28ECh. 14 - Prob. 14.29ECh. 14 - Lithium hydride, 7Li1H, is a potential fuel for...Ch. 14 - Prob. 14.31ECh. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Prob. 14.36ECh. 14 - From the data in Table 14.2, predict B for DCl D...Ch. 14 - A colleague states that the pure rotational...Ch. 14 - Prob. 14.39ECh. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Prob. 14.42ECh. 14 - Prob. 14.43ECh. 14 - Determine E for J=20J=21 for HBr assuming it acts...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Prob. 14.47ECh. 14 - Prob. 14.48ECh. 14 - Prob. 14.49ECh. 14 - Prob. 14.50ECh. 14 - Prob. 14.51ECh. 14 - Prob. 14.52ECh. 14 - Prob. 14.53ECh. 14 - Prob. 14.54ECh. 14 - Prob. 14.55ECh. 14 - Prob. 14.56ECh. 14 - Prob. 14.57ECh. 14 - Prob. 14.58ECh. 14 - Prob. 14.59ECh. 14 - Prob. 14.60ECh. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Prob. 14.63ECh. 14 - Prob. 14.64ECh. 14 - Prob. 14.65ECh. 14 - Prob. 14.66ECh. 14 - Prob. 14.68ECh. 14 - Prob. 14.69ECh. 14 - Prob. 14.70ECh. 14 - Prob. 14.71ECh. 14 - Prob. 14.72ECh. 14 - Prob. 14.73ECh. 14 - Prob. 14.74ECh. 14 - Prob. 14.75ECh. 14 - Prob. 14.76ECh. 14 - Prob. 14.77ECh. 14 - Prob. 14.78ECh. 14 - Prob. 14.79ECh. 14 - Prob. 14.80ECh. 14 - Prob. 14.81ECh. 14 - Prob. 14.82ECh. 14 - Prob. 14.83ECh. 14 - Prob. 14.84ECh. 14 - Prob. 14.85ECh. 14 - Dioctyl sulfide, (C8H17)2S, and hexadecane,...Ch. 14 - Where would you expect vibrations for ethyl...Ch. 14 - Prob. 14.88ECh. 14 - Prob. 14.89ECh. 14 - Prob. 14.90ECh. 14 - Prob. 14.91ECh. 14 - Prob. 14.92ECh. 14 - Prob. 14.93ECh. 14 - Prob. 14.94ECh. 14 - The mutual exclusion rule states that for certain...Ch. 14 - Prob. 14.96ECh. 14 - Prob. 14.97ECh. 14 - Prob. 14.98ECh. 14 - Prob. 14.99ECh. 14 - Construct and compare the energy level diagrams...Ch. 14 - Prob. 14.101E
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- Determine E, H, G, and S for CH4 at standard pressure and 25°C. σ equals 12 for methane and the atomization energy of CH4 is 1163 kJ/mol.arrow_forwardCalculate AH for the reaction: C2H4 (g) + H2 (g) → C2H6 (g), from the following data: C2H4 (g) + 3 O2 (g) → 2 CO2 (g) + 2 H2O (I) AH = -1411. kJ/mol 2 C2H6 (g) + 7 O2 (g) → 4 CO2 (g) + 6 H2O (1) AH = -3120. kJ/mol 2 H2 (g) + O2 (g) → 2 H20 (1) AH = -571.6 kJ/mol Select one: O - 136.8 kJ/mol O 1137 kJ/mol O -273.6 kJ/mol O 133.3 kJ/molarrow_forwardExplain the importance of the quantization of vibrational, rotational, and translational energy as it relates to the behavior of atoms and molecules.arrow_forward
- 5. The fundamental vibrational frequencies for 1H19F and 2D19F are 4138.52 and 2998.25 cm-1, respectively, and De for both molecules is 5.86 eV. What is the difference in the bond energy (bond dissociation energy) of the two molecules? A) 0.567 eV B) 0.15 eV C) 0.0707 eV D) 0.254 eVarrow_forwardArrange the following energies in order of increasing magnitude: a) the typical energy of a covalent single bond; b) the mean molecular translational energy for a gas at room temperature; c) the mean rotational energy of a diatomic molecule at room temperature; d) the vibrational energy for a diatomic molecule at room temperature; e) the ionization energy of H. Justify your order.arrow_forward(i) Identify the different enthalpy changes and construct the Born-Haber cycle for the formation of sodium choride (NaCl) using the information below. Calculate the missing enthalpy change value Na+(g) + Cl-(g) → NaCl (s) ∆Ho = ? Cl2 (g) → Cl (g) ∆Ho = +121 kJmol-1 Cl (g) + e- → Cl-(g) ∆Ho = -364 kJmol-1 Na (s) → Na (g) ∆Ho = +108 kJmol-1 Na (g) → Na+(g) + e- ∆Ho = +500 kJmol-1 Na (s) + Cl2 (g) → NaCl (s) ∆Ho = -411 kJmol-1arrow_forward
- 4. The vibrational frequency of 'H³°C1 is 8.963 x 1013 Hz. What is the force X constant of the bond in this molecule?arrow_forwardBriefly describe the contributions of Walter Nernst, T. W. Richards, Max Planck and G. N. Lewis in the development of the third law of thermodynamics.arrow_forwardGiven the following data PA(s) + 6C12 (9) → 4PCI3 (g) АН — — 1225.6 kJ PA(s) + 502(9) → P,O10 (s) AH = -2967.3 kJ PCI3 (g) + Cl2 (g) → PCI5 (g) АН — — 84.2 kJ PCI, (9) + 02 (9) → CI3PO(9) AĦ = -285.7 kJ Calculate AH for the reaction P,O10 (s) + 6PCI5 (9) → 10C13PO(9) ΔΗ- kJarrow_forward
- The number of nodes for the vibrational wavefunction of an excited CO is found to be 5. If the force constant of C--O is 1550 N/m, what is the vibrational energy (in kJ/mol) of the excited CO? (h= 6.626 x 10-¹4J.s) Select one or more: □ A. 78.95 kJ/mol B. 1.34 kJ/mol □ C. 103.34 kJ/mol □ D. 12.9 kJ/molarrow_forwardUse the molar bond enthalpy data in the table to estimate the value of AHxn for the equation NH, (g) + 20,(g) → HNO, (g) + H,O(g) The bonding in the molecules is shown. + H + O=O H.arrow_forward2. Calculate the enthalpy change for the reaction : C4H4 (9) + H2 (9) C2H6 (g) Given the following data: i) C2H4 (9) + 3 O2 (9) → 2 CO2 (9) + 2 H2O (1) AH° = - 1410.9 kJ 2 C2H6 (9) + 7 02 (9) →4 CO2 (9) + 6 H20 (1) ii) iii) 2 H2 (9) + O2 (g) 2 H2O (1) AH° = - 3119.4 kJ AH° = - 571.6 kJ 3. Calculate the standard enthalpy change for the reaction, C2H2 (g) + 2 H2 (9g) - C2H6 (9) Given that: i) 2 C2H2 (9) + 5 02 (g) 4 CO2 (9) + 2 H2O (1) AH° = - 2599 kJ 3119 kJ ii) 2 C2H6 (9) + 7 02 (9) - 4 CO2 (9) + 6 H20 (1) AH° = iii) 2 H2 (9) + O2 (9) → 2 H2O () AH° = - 572 kJ The enthalpy of combustion of methane is -891 kJmol-1. Calculate the enthalpy of formation of methane if the enthalpy of formation of carbon dioxide and water are - 394 kJmol-1 and -286 kJmol respectively. Chemical equation for formation of 4. methane: C(s) + 2H2(9) CH4(9) Given: AH = -891 kJmol-1 CH4(9) + 202(9) 2H2O() + CO2(g) C(s) + Oz(g) → CO2(9) H2(g) + 2 O2 - H20 AH = -394 kJmol-1 AH = -286 kJmol-1arrow_forward
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