ORGANIC CHEMISTRY (LL)-W/MOD.MASTERING.
8th Edition
ISBN: 9780134466712
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 1.4, Problem 15P
An atom with a formal charge does not necessarily have more or less electron density than the atoms in the molecule without formal charges. We can see this by examining the potential maps for H2O, H3O+, and HO–.
- a. Which atom bears the formal negative charge in the hydroxide ion?
- b. Which atom has the greater electron density in the hydroxide ion?
- c. Which atom bears the formal positive charge in the hydronium ion?
- d. Which atom has the least electron density in the hydronium ion?
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Students have asked these similar questions
Why don't we draw double bonds between the Be atom and the Cl atoms in BeCl2?
That would give positive formal charges to the chlorine atoms and a negative formal charge to the beryllium atom.
There aren't enough electrons.
That would result in more than eight electrons around beryllium.
That would result in more than eight electrons around each chlorine atom.
That would result in the formal charges not adding up to zero.
Carbon Thioxide (OCS)
d) determine the partial charges of the CO bond
e) determine the direction of the polarity arrow for the CO bond
f) determine the polarity of the Carbon Thioxide molecule
g) determine the oxidation state (charge) of the C in the ion
h) determine the formal charge of all the atoms in carbon Thoxide molecule
i) is the structure the optimum formal charge, if not draw the optimum formal charge structure
j) What is the electron domain for the C (VSEPR)
k) What is the geometric domain for the C
l) what is the hybridization of the C
- What orbital(s) are the lone pairs of electrons on the O atom placed?
- What orbital is the lone pair of electrons on the N atom placed?
- What type of bond(s) are formed between Ca1 – C?
- What type of bond(s) are formed between C = O?
- What type of bond(s) are formed between C – N?
- What type of bond(s) are formed between N – Ca2?
- What type of bond(s) are formed between N – H?
- What is the angle between Ca1 – C = O?
- What is the angle between Ca1 – C – N?
- What is the angle between O = C – N?
- What is the angle between C – N – Ca2?
Chapter 1 Solutions
ORGANIC CHEMISTRY (LL)-W/MOD.MASTERING.
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
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