The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s. Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types: Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital. Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital. Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital. Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Question

Want to see the full answer?

Answer 1

Question

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 2

Question

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 6

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 7

Chapter 14, Problem 41E

Interpretation Introduction

Interpretation: The overlapping of 1s atomic orbital of H and 2p atomic orbital overlap of F to form bonding and anti-bonding MO’s to form HF molecule needs to be explained and the orbitals needs to be labeled as s and p MO’s.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 14 - Prob. 1DQ Ch. 14 - Prob. 2DQ Ch. 14 - Prob. 3DQ Ch. 14 - Prob. 4DQ Ch. 14 - Prob. 5DQ Ch. 14 - Prob. 6DQ Ch. 14 - Compare and contrast the MO model with the LE...Ch. 14 - Prob. 8DQ Ch. 14 - Prob. 9E Ch. 14 - Prob. 10E

Solution Summary: The author explains that the overlapping of 1s atomic orbital of H and 2p atomial overlap of F to form bonding and anti-bonding MO's is explained.

Videos

Want to see the full answer?

Chapter 14 Solutions