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(a)
Interpretation:
The disulfide formed on oxidizing the following thiol should be determined:
Concept Introduction:
Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.
Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.
(b)
Interpretation:
The disulfide formed on oxidizing the following thiol should be determined:
Concept Introduction:
Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.
Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.
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Chapter 14 Solutions
Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
- 50. If this molecule was heated, which carboxyl group will be readily lost as carbon dioxid. C HO2C CO2H CO2H HO2C B a. b. B C. C d.arrow_forwardWhat is produced when most aldehydes undergo Grignard reaction? O A. primary alcohol B. secondary alcohol O C. tertiary alcohol O D. no reaction 2.arrow_forwardWrite the complete chemical reaction and correct chemical formula and structure of the following: 1. Autooxidation of benzaldehyde 2. reaction between acetic acid and ethanol 3. reaction between aspirin and sodium hydroxide 4. reaction of acetone with methanolarrow_forward
- Give the IMPAC name for each compound. 1. COOH COOH 2. Br 3. CH3 CHz COOHarrow_forward53. Which statement below is incorrect? а. the smallest aldehyde has the formula HCOH b. a carbonyl carbon consists of a carbon-oxygen double bond in an aldehyde, the carbonyl carbon is always bonded to a hydrogen atom с. d. Ketones are more soluble in water than alcohols with the equiva lent number of carbonsarrow_forward69. The structure of the aldehyde or ketone that the following compound came from: H A. III only B. IV only C. I and IV D. II only IVarrow_forward
- ● Arrange these compounds in order of increasing boiling point. Heptane HO. LOH 1,5-Pentanediol Propanol 1-Hexanol LOHarrow_forwardWhat is produced when methanal undergoes Grignard reaction? O A. primary alcohol B. secondary alcohol O C. tertiary alcohol O D. no reactionarrow_forward9. Label the following reactions as: A. ionization of a carboxylic acid in water B. neutralization of a carboxylic acid with a base C. formation of an ester D. acid-catalyzed hydrolysis of an ester E. ionization of an amine in water F. neutralization of an amine with an acid G. formation of an amide H. hydrolysis of an amide CH3NH₂ + HCI CH3NH3 Cl CH3CH₂CNHCH 3 HOH CH₂COH CH3COH+ NaOH →→→→ CHICOH heat CHICOH CH3COH + CH3NH₂ CH₂COH CH3CH₂COCH₂CH₂CH + HOHH CH3CH₂COH + HOCH₂CH₂CH3 CHO + H₂O - CH3CO heat CHO CH₂CO *Na + HOH CH3NH₂ + H₂0 CH3NH3* + OH- + H3O+ CH3CH₂C + NH2CH3 R-H R-O-H CH3CNHCH3 + HOH R-N- I O CH₂COH CH3COH + HOCH3 CH3COCH3 + HOH сно сосни, O || R-C-R O 11 R-C-O-R Hydrocarbons Alcohols Amines Ketones Esters R-X R-O-R 0=0|0=0|0=0 R-C-H R-C-0-H R-C-N- I Alkyl halides Ethers Aldehydes Carboxylic Acids Amidesarrow_forward
- Rank the compounds in each group in order of increasing boiling point. a. CH 3CH 2CH 2I, CH 3CH 2CH 2Cl, CH 3CH 2CH 2F b. CH 3(CH 2) 4CH 3, CH 3(CH 2) 5Br, CH 3(CH 2) 5Clarrow_forwardExplain why methyl alcohol is soluble in water in all proportions, while stearyl alcohol [CH3(CH2)16OH] is a waxy solid that is not soluble in water.arrow_forwardThe foul odor of rancid butter is caused by butyric acid, CH3CH2CH2CO2H. (a) Draw the Lewis structure and determine the oxidation number and hybridization for each carbon atom in the molecule. (b) The esters formed from butyric acid are pleasant-smelling compounds found in fruits and used in perfumes. Draw the Lewis structure for the ester formed from the reaction of butyric acid with 2-propanol.arrow_forward
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