Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 14.2, Problem 2P
Interpretation Introduction
Interpretation:
Initiation, propagation and termination steps for the monochlorination of cydohexane should be written.
Concept introduction:
Radical or free radical:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
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Chapter 14 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 14.2 - Write the mechanism for the monobromination of...Ch. 14.2 - Prob. 2PCh. 14.4 - Prob. 3PCh. 14.4 - Which of the hydrogens in the structure in the...Ch. 14.4 - How many alkyl chlorides can be obtained from...Ch. 14.4 - Prob. 7PCh. 14.5 - Prob. 9PCh. 14.6 - a. Which ether is most apt to form a peroxide? b....Ch. 14.7 - Prob. 11PCh. 14 - Prob. 12P
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- 2-chloropropane is a major product of the reaction of chlorine with propane under ultraviolet light. Write the mechanism for this reaction including the initiation step and the two propagation steps.arrow_forwardConsider the free radical mono-chlorination of ethane: a) Write the initiation step b) Write two propagation steps c) Write two termination steps that involve the ethyl radical.arrow_forwardIn alkane free-radical halogenation, the mechanistic (arrow pushing) step that transfers the radical to the alkane is called __________________ . A. propagation B. initiation C. termination D. sublimationarrow_forward
- Write a mechanism for the acid-catalyzed addition of water to 2-butenearrow_forwardWrite a pair of chain propagation steps for the radical bromination of propane to give 1-bromopropane. Then calculate ▲H° for each propagation step and for the overall reaction.arrow_forwardEach step of the propagation portion of the reaction mechanism for free radical chlorination uses _________ and produces __________. a radical; the product a carbocation, a radical a molecule of chlorine; hydrochloric acid a radical; a radical an alkyl halide; an alkyl halidearrow_forward
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