Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum. Concept introduction: An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C ) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

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Answer 1

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Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

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Which molecule, HCl or HBr will have a higher energy IR absorption? Explain. (Hint, the spring force constant for the bonds in these two molecules are similar.)

Question 3: Determine which unkown the following spectra depicts

Answer 2

Question

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

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Answer 3

Question

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

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Answer 4

Question

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

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Answer 5

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

Answer 6

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

Answer 7

Chapter 15, Problem 15.20P

Interpretation Introduction

Interpretation:

Based on the intensities of the C=C stretching bands, each of the compounds shown are to be matched with its IR spectrum.

Concept introduction:

An oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar. A stretching mode involving a nonpolar bond (such as C=C) tends to have a weak or nonexistent IR absorption unless the two portions of the molecule connected by that bond are highly dissimilar.

Answer 8

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Answer 10

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Answer 11

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Prob. 15.6P Ch. 15 - Prob. 15.7P Ch. 15 - Prob. 15.8P Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that an oscillating dipole moment tends to be more pronounced for a stretching vibration when the bond is polar.

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Chapter 15 Solutions