General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 15, Problem 15.22P
Interpretation Introduction

Interpretation:

The atmospheric pressure when water boils at 93°C has to be determined.

Concept Introduction:

If P1 and P2 are the vapor pressures at two temperatures  T1 and  T2 then they are related by Clausius-Clapeyron Equation as follows:

  ln(P1P2)=ΔHvapR(1T21T1)

If enthalpy of vaporization and vapor pressure at one temperature is known then this equation can be used to estimate the vapor pressure at other temperature.

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