Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 15.2, Problem 6P
Interpretation Introduction
Interpretation: To choose the correct option of the given statements.
Concept introduction: Delocalization energy is nothing else it is the energy released when deloclization
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Which is a correct statement? A. The delocalization energy of an ester is about 18 kcal/mol, and the delocalization energy of an amide is about 10 kcal/mol. B. The delocalization energy of an ester is about 10 kcal/mol, and the delocalization energy of an amide is about 18 kcal/mol.
___ is an example of an alkyl halide.
Select one:
a. KCl
b. CHCl3
c. NaCl
d. CF2=CF2
1) identify the reactant/s in the chemical equation and circle it, also name its major functional group
2) identify the product/s in the chemical equation (circle it) and name its functional group
3) is the a reversible reaction or not? How do we know
Chapter 15 Solutions
Organic Chemistry (8th Edition)
Ch. 15.1 - The aromas of many flowers and fruits are due to...Ch. 15.1 - Name the following:Ch. 15.1 - Prob. 3PCh. 15.2 - Which is longer, the carbon-oxygen single bond in...Ch. 15.2 - There are three carbon-oxygen bonds in methyl...Ch. 15.2 - Prob. 6PCh. 15.4 - a. What is the product of the reaction of acetyl...Ch. 15.4 - What is the product of an acyl substitution...Ch. 15.5 - a. Which compound has the stretching vibration for...Ch. 15.5 - Using the pKa values listed in Table 15.1, predict...
Ch. 15.5 - Is the following statement true or false? If the...Ch. 15.6 - Starting with acetyl chloride, what neutral...Ch. 15.6 - Prob. 13PCh. 15.7 - Starting with methyl acetate, what neutral...Ch. 15.7 - We saw that it is necessary to use excess amine in...Ch. 15.7 - Prob. 17PCh. 15.7 - Which ester hydrolyzes more rapidly? a. methyl...Ch. 15.7 - a. state three factors that cause the uncatalyzed...Ch. 15.8 - Prob. 21PCh. 15.8 - Using the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 23PCh. 15.8 - Show the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 25PCh. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.9 - Prob. 28PCh. 15.9 - Prob. 29PCh. 15.10 - Show how each of the following esters could he...Ch. 15.10 - Prob. 32PCh. 15.11 - Prob. 33PCh. 15.11 - Which of the following reactions leads to the...Ch. 15.12 - Prob. 35PCh. 15.12 - Prob. 36PCh. 15.13 - Prob. 37PCh. 15.14 - Prob. 38PCh. 15.14 - Prob. 39PCh. 15.15 - Prob. 40PCh. 15.15 - Which alkyl halides from the carboxylic acids...Ch. 15.16 - Prob. 43PCh. 15.16 - Prob. 44PCh. 15.16 - Prob. 45PCh. 15.17 - Prob. 46PCh. 15.18 - How could you synthesize the following compounds...Ch. 15 - Prob. 48PCh. 15 - Name the following:Ch. 15 - Prob. 50PCh. 15 - What compound are obtained from the fallowing...Ch. 15 - a. Rank the following esters in order of...Ch. 15 - Because bromocyclohexane is a secondary alkyl...Ch. 15 - a. Which compound would you expect to have a...Ch. 15 - How could you use 1H NMR spectroscopy to...Ch. 15 - Rank the following compounds in order of...Ch. 15 - Prob. 57PCh. 15 - Prob. 58PCh. 15 - Prob. 59PCh. 15 - A compound with molecular formula C5H10O2 gives...Ch. 15 - Prob. 61PCh. 15 - Prob. 62PCh. 15 - Prob. 63PCh. 15 - Prob. 64PCh. 15 - Prob. 65PCh. 15 - Prob. 66PCh. 15 - Two products, A and B, are obtained from the...Ch. 15 - Prob. 68PCh. 15 - Prob. 69PCh. 15 - Prob. 70PCh. 15 - Prob. 71PCh. 15 - Prob. 72PCh. 15 - When treated with an equivalent of methanol,...Ch. 15 - a. Identify the two products obtained from the...Ch. 15 - Prob. 75PCh. 15 - Prob. 76PCh. 15 - a. When a carboxylic acid is dissolved in...Ch. 15 - Prob. 78PCh. 15 - Identity the major and minor products of the...Ch. 15 - When a compound with molecular formula C11H14O2...Ch. 15 - Prob. 81PCh. 15 - Prob. 82PCh. 15 - Prob. 83PCh. 15 - The 1H NMR spectra for two esters with molecular...Ch. 15 - Show how the following compounds could be prepared...Ch. 15 - Prob. 86PCh. 15 - Prob. 87PCh. 15 - The intermediate shown here is formed during the...Ch. 15 - Prob. 89PCh. 15 - Propose a mechanism that accounts for the...Ch. 15 - Catalytic antibodies catalyze a reaction by...Ch. 15 - Prob. 92P
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- which are acetals, hemi-acetals, ketals, or hydrates?arrow_forwardMolecule Type Boiling point (°C) CH3CH2CH3 Alkane -42 CH3CHO Aldehyde +21 CH3CH2OH Alcohol +78 i. Why is the boiling point of the aldehyde greater than that of the alkane?ii. Why is the boiling point of alcohol the highest?iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.arrow_forwarddraw the alkyl halide and the alkoxide ion.arrow_forward
- Draw out 3 molecules of CH3NH2 showing the strongest interactions that are present between the molecules.arrow_forwardUsing the Functional Group and Reagent to Identity the Type of Reaction Draw the product of each reaction.arrow_forwardConsider the synthesis scheme in Figure 38. What type of compound is represented by C in the synthesis scheme? * Nitrile Carboxylic acid Acyl halide Ester Amidearrow_forward
- -What is the IUPAC name of the product? a. Pentanoyl chloride b.Pentanoic acid chloride c. Pentanone chloride d. Pentanyl chloride -What type of reaction is illustrated in the reaction mechanism? a. Nucleophilic acyl substitution reaction b. Electrophilic substitution reaction c. Electrophilic acyl substitution reaction d. Nucleophilic addition reaction -What is the main functional group of the organic molecule? a. Carboxyl functional group b. Aldehyde functional group c. Carbonyl functional group d. Alcohol functional group -Aside from the organic molecule, what product is formed in the reaction? a. Hydronium ion b. Hydroxide anion c. Water molecule d. Hydroxyl group -The illustrated reaction mechanism is considered __________. a. Step-wise b. Unfavorable c. Concerted d. Continuous -Which atom in the reaction mechanism is the nucleophile? a. Chloride anion b. Carboxyl carbon c. Hydroxyl group d. Methyl group -What is the type of hybridization of the carboxyl carbon in the mechanism?…arrow_forwardWhat is organic chemistry? Select one: a. Organic chemistry is the sub-discipline of chemistry that focuses on large molecules only. b. Organic chemistry is the sub-discipline of chemistry that focuses on molecules that do not contain carbon. c. Organic chemistry is the sub-discipline of chemistry that focuses on hydrogen and hydrogen-containing molecules. d. Organic chemistry is the sub-discipline of chemistry that focuses on carbon and carbon-containing molecules.arrow_forwardName of product for each reactionarrow_forward
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