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Concept explainers
(a)
Interpretation:
The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:
Concept Introduction:
In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a
(b)
Interpretation:
The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:
(CH3)2CHCH2CH2OH
Concept Introduction:
In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an
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Chapter 16 Solutions
Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
- Which of the following is not a physical property of alcohols or phenols? Select one: A. The solubilities of primary alcohols in water decrease with increasing molecular weight. B. Phenols are generally only slightly soluble in water. C. Due to hydrogen bonding, boiling points of alcohols are much higher than those of corresponding alkanes. D. The hydroxyl group of an alcohol is nonpolar.arrow_forwardWhat is produced when methanal undergoes Grignard reaction? O A. primary alcohol B. secondary alcohol O C. tertiary alcohol O D. no reactionarrow_forwardClassify each alcohol as to 1º, 2º, or 3º 1. 2. CH3CH2CH(CH3)CH2OHCH3 3. CH2CH2CHOHCH3arrow_forward
- 2. Complete the following reactions for the preparation of alcohols. Draw the structure of the product. Name the reactant and the product. a) CHy CH=CH-CHy + HyO Hydration of alkenes b) Cat. CHy-CHy + H2 drogenation carbonyl pups d)arrow_forwardGive the IMPAC name for each compound. 1. COOH COOH 2. Br 3. CH3 CHz COOHarrow_forward18. Ketone reduction Dicyclohexyl ketone Reduce the ketone. 1. NaBH4, ethanol 2. H3O+ H OH Dicyclohexylmethanol (88%) (a 2° alcohol)arrow_forward
- Write the complete equation for the dehydration reaction of the following alcohols. If more than one product can be formed, and one of the products is the major product, clearly indicate which one is the major product. If no dehydration reaction can occur, you must clearly indicate this by writing "no reaction" CH,CH, OH a. b. CH, CHCH, CH CH,CH, CH, OHarrow_forwardDraw the products formed when each alcohol is oxidized with K 2Cr 2O 7. In some cases, no reaction occurs.arrow_forwardWhat products are formed when each alcohol is oxidized with K 2Cr 2O 7? In some cases, no reaction occurs.arrow_forward
- An acid catalyst in nucleophilic addition of aldehydes and ketones is used for: Select one: a. Protonation of carbonyl carbon b. Making the aldehyde and ketone more susceptible to nucleophiles c. Increasing the nucleophilicity of the nucleophile d. To provide a medium for the reaction.arrow_forward1. Draw the following compounds. c. (Z)-2-methylpent-2-enol d. ethylpropanoatearrow_forwardWhich of the following is not a physical property of alcohols or phenols? A. The solubilities of primary alcohols in water decrease with increasing molecular weight. B. Due to hydrogen bonding, boiling points of alcohols is much higher than those of corresponding alkanes. C. The hydroxyl group of an alcohol is nonpolar. D. Phenols are generally only slightly soluble in water.arrow_forward
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