To identify the functional groups in Warfarin. Concept Introduction: A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups. A stereo centre is the centre where all the 4 groups attached to a carbon are different. A keto group stays in the equilibrium with its enol (−OH) form by resonance. NaBH 4 is a reducing agent it reduces ketone or aldehyde to an alcohol.

Question

Which statement is correct? a. Testosterone and nortestosterone possess a ketone at C-3 conjugated to a single bond at C-4 and a hydroxyl at C-17b. b. Testosterone and nortestosterone possess a ketone at C-4 conjugated to a double bond at C-3 and a hydroxyl at C-17b. c. Testosterone and nortestosterone possess a ketone at C-3 conjugated to a double bond at C-4 and a hydroxyl at C-17b. d. The obviously wrong answer!.

Answer 1

Question

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Which statement is correct? a. Testosterone and nortestosterone possess a ketone at C-3 conjugated to a single bond at C-4 and a hydroxyl at C-17b. b. Testosterone and nortestosterone possess a ketone at C-4 conjugated to a double bond at C-3 and a hydroxyl at C-17b. c. Testosterone and nortestosterone possess a ketone at C-3 conjugated to a double bond at C-4 and a hydroxyl at C-17b. d. The obviously wrong answer!.

Answer 2

Question

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Answer 3

Question

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Expert Solution & Answer

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Answer 4

Question

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Expert Solution & Answer

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Answer 5

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 6

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 7

Chapter 17, Problem 17.46P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 8

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 9

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 10

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 11

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 12

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 13

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 14

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 15

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 16

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Answer 27

Ch. 17.2 - Problem 17-1 Wrtie the IUPAC name for each...Ch. 17.2 - Prob. 17.2P Ch. 17.2 - Prob. 17.3P Ch. 17.4 - Prob. 17.4P Ch. 17.4 - Prob. 17.5P Ch. 17.4 - Problem 17-6 Show the reaction of benzaldehyde...Ch. 17.4 - Problem 17-7 Identify all hemiacetals and acetals...Ch. 17.5 - Prob. 17.8P Ch. 17 - 17-9 Answer true or false. (a) The one aldehyde...Ch. 17 - Prob. 17.10P

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