(a) Interpretation: The reason as to why the trityl radical is an unusually stable radical is to be stated. Concept introduction: Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π - bonds or by interaction of the lone pair of electrons and π - bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Answer 1

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

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Answer 2

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Expert Solution & Answer

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Answer 3

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

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Answer 4

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

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Answer 5

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 6

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 7

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains that the trityl radical is an unusually stable radical because it is stabilized by the resonance effect of the three phenyl rings.

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Chapter 17 Solutions