CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Chapter 17, Problem 90CP
Lactams can be hydrolyzed with base, just like other amides. When a lactam is hydrolyzed, the ring is opened to form a product with two 
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What amine is formed by reduction of each amide?
a.Primary amides tend to exist as dimers in the solid and liquid state.
b.Dimethylacetamide, CH3CON(CH3)2 has a higher boiling point than acetamide.
c.Nitrile is often classified as an acid derivative because it is hydrolyzed to a -COOH.
d.Esters have lower boiling points than ketones of comparable molecular masses.
Whice are correct?
Amines with more than 6 carbons are soluble in:
a) aqueous HCI
b) aqueous NaHCO3
d) water
c) aqueous NaOH
Which of the following would give a positive iodoform test?
acetone
a) benzophenone
c) 3-pentanone
d) cyclopentanone
meth
"Saponification" as the term is used in organic chemistry means:
a) acidic hydrolysis of an ester
b) basic hydrolysis of an ester
c) acidic hydrolysis of an amide
d) basic hydrolysis of an amide
3. (
Propylamine can be synthesized by the LiAlH4 reduction of:
a) CH3CH2CECH
b) CH3CH=NH
d)) CH3CH2CEN
c) CH3CH2NO2
Chapter 17 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 17.1 - Draw out each compound to clearly show what groups...Ch. 17.1 - Prob. 17.2PCh. 17.1 - (a) Label each functional group in lisinopril, a...Ch. 17.2 - Give the IUPAC name for each compound. a. b. c.Ch. 17.2 - Give the structure corresponding to each IUPAC...Ch. 17.2 - Prob. 17.5PCh. 17.2 - Give an acceptable name for each ester. a. CH3(...Ch. 17.2 - Prob. 17.6PCh. 17.2 - Prob. 17.7PCh. 17.2 - Prob. 17.8P
Ch. 17.2 - Prob. 17.9PCh. 17.3 - Which compound in each pair has the higher boiling...Ch. 17.4 - Prob. 17.11PCh. 17.5 - In addition to ethyl butanoate (Section 17.5),...Ch. 17.6 - Prob. 17.3PPCh. 17.6 - Prob. 17.13PCh. 17.6 - Which compound ¡n each pair ¡s more water soluble?...Ch. 17.6 - Prob. 17.5PPCh. 17.6 - Prob. 17.14PCh. 17.6 - Prob. 17.15PCh. 17.7 - Ibuprofen is another pain reliever that is a...Ch. 17.8 - Prob. 17.6PPCh. 17.8 - Prob. 17.17PCh. 17.8 - Prob. 17.18PCh. 17.8 - Prob. 17.7PPCh. 17.8 - Prob. 17.19PCh. 17.9 - Prob. 17.8PPCh. 17.9 - Prob. 17.20PCh. 17.9 - Prob. 17.21PCh. 17.9 - Prob. 17.22PCh. 17.9 - Prob. 17.9PPCh. 17.9 - Prob. 17.23PCh. 17.9 - Prob. 17.24PCh. 17.10 - Prob. 17.10PPCh. 17.10 - Prob. 17.25PCh. 17.11 - Prob. 17.26PCh. 17 - Prob. 27PCh. 17 - Prob. 28PCh. 17 - Prob. 29PCh. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - Prob. 33PCh. 17 - Prob. 34PCh. 17 - Prob. 35PCh. 17 - Give an acceptable name for each ester. a. CH3CO2(...Ch. 17 - Prob. 37PCh. 17 - Prob. 38PCh. 17 - Prob. 39PCh. 17 - Prob. 40PCh. 17 - Prob. 41PCh. 17 - Prob. 42PCh. 17 - Prob. 43PCh. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - Prob. 52PCh. 17 - Prob. 53PCh. 17 - Prob. 54PCh. 17 - What ester is formed when butanoic acid...Ch. 17 - Prob. 56PCh. 17 - Prob. 57PCh. 17 - Prob. 58PCh. 17 - Prob. 59PCh. 17 - Prob. 60PCh. 17 - Prob. 61PCh. 17 - Prob. 62PCh. 17 - Prob. 63PCh. 17 - Prob. 64PCh. 17 - Prob. 65PCh. 17 - Prob. 66PCh. 17 - What products are formed when each ester is...Ch. 17 - Prob. 68PCh. 17 - Prob. 69PCh. 17 - Prob. 70PCh. 17 - Prob. 71PCh. 17 - Prob. 72PCh. 17 - Prob. 73PCh. 17 - Prob. 74PCh. 17 - Draw the products formed in each reaction. a. b....Ch. 17 - Draw the products formed in each reaction. a. b....Ch. 17 - Answer the following questions about A, depicted...Ch. 17 - Answer the following questions about B, depicted...Ch. 17 - Prob. 79PCh. 17 - Prob. 80PCh. 17 - Prob. 81PCh. 17 - Prob. 82PCh. 17 - Prob. 83PCh. 17 - Prob. 84PCh. 17 - Prob. 85PCh. 17 - Prob. 86PCh. 17 - Prob. 87PCh. 17 - Prob. 88PCh. 17 - Prob. 89CPCh. 17 - Lactams can be hydrolyzed with base, just like...
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- How acid chlorides, anhydrides, esters, and amides are prepared ?arrow_forwardN-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomersarrow_forwardWhat is the product when Methyl phenylacetate reacts with NH3 and ether in order to form amide?arrow_forward
- Amides do not react with halide ions. Why?arrow_forwardThe hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)arrow_forwardWhen amines are reacted with bases, they form ammonium salts. Is that true or false?arrow_forward
- 1. What are examples of amine compounds that are commonly found in nature and discuss their functions and properties briefly. 2. Show the structure of your example and give its IUPAC name. 3. Describe the reactions that amines may undergo.arrow_forwardHow a Carboxylic Acid and an Amine Undergo an Acid–Base Reaction?arrow_forwardThe reaction of a carboxylic acid with a primary amine produces what organic product? A) primary amide B) secondary amide C) tertiary amide D) quaternary amide E) ammoniaarrow_forward
- Draw the amide formed when 1-methylethylamine (CH3CH(CH3)NH2) is heated with each carboxylic acid.arrow_forwardWhich of the following is true of hydrogen bonding in amines? a) Amines do not form hydrogen bonds because there is no difference in the electronegativities of nitrogen and hydrogen. b) The N—H> N hydrogen bond is stronger than the O—H> O hydrogen bond. c) The N—H> N hydrogen bond is the same strength as that of O—H> O hydrogen bond. d) The N—H> N hydrogen bond is weaker than the O—H> O hydrogen bond.arrow_forwardAcetaminophen is an analgesic marketed under the brand name Tylenol, among others. Draw the amine that results from the base hydrolysis of acetaminophen.arrow_forward
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