Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

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Chapter 17 Solutions

Organic Chemistry (9th Edition)

Ch. 17.8 - Draw all the resonance forms of the sigma complex...Ch. 17.9 - Predict the mononitration products of the...Ch. 17.9 - Predict the mononitration products of the...Ch. 17.9 - Prob. 17.14PCh. 17.10 - Propose products (if any) and mechanisms for the...Ch. 17.10 - Predict the products (if any) of the following...Ch. 17.10 - Which reactions will produce the desired product...Ch. 17.10 - Prob. 17.19PCh. 17.11C - Prob. 17.20PCh. 17.12A - Prob. 17.21PCh. 17.12B - Propose a mechanism that shows why p-chlorotoluene...Ch. 17.12B - Propose mechanisms and show the expected products...Ch. 17.12B - Prob. 17.24PCh. 17.13A - What products would you expect from the following...Ch. 17.13A - What organocuprate reagent would you use for the...Ch. 17.13B - What products would you expect from the following...Ch. 17.13B - Prob. 17.28PCh. 17.13C - What products would you expect from the following...Ch. 17.13C - Prob. 17.30PCh. 17.14C - Prob. 17.31PCh. 17.14C - Predict the major products of the following...Ch. 17.15A - Predict the major products of treating the...Ch. 17.15B - Prob. 17.34PCh. 17.15B - Prob. 17.35PCh. 17.15B - Predict the major products when the following...Ch. 17.15C - Prob. 17.37PCh. 17.15C - a. Based on what you know about the relative...Ch. 17.15C - Show how you would synthesize the following...Ch. 17.16A - The bombardier beetle defends itself by spraying a...Ch. 17.16B - Predict the products formed when m-cresol...Ch. 17.16B - Prob. 17.42PCh. 17.16B - Prob. 17.43PCh. 17.16B - Predict the site(s) of electophilic attack on...Ch. 17.16B - Prob. 17.45PCh. 17.16B - Prob. 17.46PCh. 17.16B - Propose a synthetic sequence of this...Ch. 17.16B - Prob. 17.48PCh. 17.16B - Starting from toluene, propose a synthesis of this...Ch. 17 - Prob. 17.50SPCh. 17 - Prob. 17.51SPCh. 17 - Show how you would synthesize the following...Ch. 17 - Predict the major products of the following...Ch. 17 - Predict the major products of bromination of the...Ch. 17 - What products would you expect from the following...Ch. 17 - Prob. 17.56SPCh. 17 - Prob. 17.57SPCh. 17 - The following compound reacts with a hot,...Ch. 17 - Prob. 17.59SPCh. 17 - Electrophilic aromatic substitution usually occurs...Ch. 17 - Prob. 17.62SPCh. 17 - The most common selective herbicide for killing...Ch. 17 - Furan undergoes electrophilic aromatic...Ch. 17 - Prob. 17.65SPCh. 17 - Bisphenol A is an important component of many...Ch. 17 - Prob. 17.67SPCh. 17 - Prob. 17.68SPCh. 17 - Prob. 17.69SPCh. 17 - In Chapter14, we saw that Agent Orange contains...Ch. 17 - Phenol reacts with three equivalents of bromine in...Ch. 17 - Prob. 17.72SPCh. 17 - Prob. 17.73SPCh. 17 - A common illicit synthesis of methamphetamine...Ch. 17 - Prob. 17.75SPCh. 17 - Prob. 17.76SPCh. 17 - Prob. 17.77SPCh. 17 - Prob. 17.78SP
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