The conditions used for nitration and the form of aniline present under those conditions. Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated. Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 ο C . The major product is meta isomer because nitro group is electron with-drawing substituent.

Question

Want to see the full answer?

Answer 1

Question

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

what would the best reagents be? And why?

Explain the Nitration ?

The reaction of a nitrile with an alcohol in the presence of a strong acid forms an N-substituted amide. This reaction, known as the Ritter reaction, doesnot work with primary alcohols. a. Why does the Ritter reaction not work with primary alcohols? b. Provide an explanation for why an amide is less susceptible to nucleophilic attack than its corresponding ester.

Answer 2

Question

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 6

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 7

Chapter 17.7, Problem 17.10P

(a)

Interpretation Introduction

To determine: The conditions used for nitration and the form of aniline present under those conditions.

Interpretation: The conditions used for nitration and the form of aniline present under those conditions are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 8

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 9

(b)

Interpretation Introduction

To determine: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product.

Interpretation: The reason for nitration of aniline being sluggish and formation of meta substituted isomer as major product are to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 10

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 11

(c)

Interpretation Introduction

To determine: The reason for formation of major para substituted product during nitration of acetanilide.

Interpretation: The reason for formation of major para substituted product during nitration of acetanilide is to be stated.

Concept introduction: The reactivity of nitrobenzene toward electrophilic aromatic substitution is less than benzene. More concentrated sulfuric and nitric acid is required for nitration of nitrobenzene. The temperature is also above 100 οC. The major product is meta isomer because nitro group is electron with-drawing substituent.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

Solution Summary: The author analyzes the reactivity of nitrobenzene toward electrophilic aromatic substitution and the formation of meta substituted isomer as major product.

Want to see the full answer?

Chapter 17 Solutions