Concept explainers
(a)
Interpretation:
The
Concept introduction:
The number of unshared valence electrons on the metal is the number
Answer to Problem 18.9P
The
Explanation of Solution
The formula for calculation of
The formula for the calculation of oxidation state is given below
• n is the number of ligands.
•
•
•
Therefore, the oxidation state of
Now, valence electronic configuration of
L-type ligands have no effect on the
Value of
Therefore, the given complex is a
The value of
(b)
Interpretation:
The
Concept introduction:
The number of unshared valence electrons on the metal is the number
Answer to Problem 18.9P
The
Explanation of Solution
The formula for calculation of
The oxidation state of the metal is calculated by the formula given below.
Since phosphine is a neutral ligand and there is no overall charge on the complex.
The formula for the calculation of oxidation state is given below
• n is the number of ligands
•
•
•
So, the oxidation state of Pd in the complex is calculated as shown below.
Now, valence electronic configuration of
Value of
Therefore, the given complex is a
The value of
(c)
Interpretation:
The
Concept introduction:
The number of unshared valence electrons on the metal is the number
Answer to Problem 18.9P
The
Explanation of Solution
The given complex is shown below.
Figure 1
The formula for calculation of
The oxidation state of metal is calculated by the formula given below.
Since, phosphine is a neutral ligand.and there is no overall charge on the complex. The charge assosciated with chlorine and hydride ligands is
The formula for the calculation of oxidation state is given below.
• n is the number of ligands.
•
•
•
So, the oxidation state of Rh in the complex is calculated below.
The valence electronic configuration of Rh is
Value of
Therefore, the given complex is a
The value of
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Chapter 18 Solutions
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
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