The product of the given reaction. Interpretation: The product of the given reaction is to be predicted. Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH 4 to give product primary alcohol. Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

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Answer 5

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Answer 6

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

Answer 7

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom.

Answer 8

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 9

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the aldehyde as a product.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 10

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 11

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as ketone.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 12

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 13

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.

Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom

Answer 14

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Answer 15

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Answer 16

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Answer 17

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.

Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 18.3 - Give the IUPAC name and (if possible) a common...Ch. 18.5D - NMR spectra for two compounds are given here,...Ch. 18.5D - Why were no products from the McLafferty...Ch. 18.5D - Use equations to show the fragmentation leading to...Ch. 18.5E - Prob. 18.5P Ch. 18.7D - Show how you would synthesize each compound from...Ch. 18.8 - Prob. 18.7P Ch. 18.9 - Predict the products of the following reactions....Ch. 18.9 - Show how the following transformations may be...Ch. 18.10 - Prob. 18.10P

Solution Summary: The author describes the reaction of acid chloride with strong reducing agent to give product primary alcohol.

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Chapter 18 Solutions