EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 18.9, Problem 18.27P
Interpretation Introduction
Interpretation:
The
Concept Introduction:
Amines and alcohols are the
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Classify the amine in morphine as 1 °, 2 °, or 3 °.
The following amines have the same molecular formula (C5H13N), but their boiling points are significantly different.
Explain why.
H
`NH2
2-Methylbutan-1-amine
Boiling point = 97 °C
N-Methylbutan-2-amine
Boiling point = 84 °C
N-Ethyl-N-methylethan-1-amine
Boiling point = 65 °C
True or False
Amine salts have increased solubility in water.
Amines have a pleasant floral aroma.
Carboxylic acids have significantly higher boiling points than alcohols of comparable molecular weight
Butanal would have a higher boiling point than butanoic acid.
Pentanone would have a lower boiling point than pentane.
Carboxylate ions have decreased solubility in water.
Chapter 18 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 18.1 - Prob. 18.1PCh. 18.1 - Prob. 18.2PCh. 18.1 - Prob. 18.3PCh. 18.1 - Prob. 18.4PCh. 18.2 - Prob. 18.5PCh. 18.2 - Prob. 18.6PCh. 18.2 - Prob. 18.7PCh. 18.3 - Prob. 18.8PCh. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.10P
Ch. 18.5 - Prob. 18.11PCh. 18.5 - Prob. 18.12PCh. 18.5 - Prob. 18.13PCh. 18.6 - Prob. 18.14PCh. 18.6 - Prob. 18.15PCh. 18.6 - Prob. 18.16PCh. 18.6 - Name each ammonium salt. a. ( CH3 NH3)+Cl b. [( CH...Ch. 18.6 - Prob. 18.18PCh. 18.6 - Prob. 18.19PCh. 18.7 - Prob. 18.20PCh. 18.7 - Prob. 18.21PCh. 18.8 - Prob. 18.22PCh. 18.8 - Prob. 18.23PCh. 18.8 - Prob. 18.24PCh. 18.9 - Prob. 18.25PCh. 18.9 - Prob. 18.26PCh. 18.9 - Prob. 18.27PCh. 18.10 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Prob. 18.30PCh. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Prob. 18.36PCh. 18 - Prob. 18.37PCh. 18 - Prob. 18.38PCh. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b. c....Ch. 18 - Give an acceptable name for each amine. a. CH3(...Ch. 18 - Prob. 18.43PCh. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Prob. 18.48PCh. 18 - Prob. 18.49PCh. 18 - Prob. 18.50PCh. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Draw the hydrogen-bonding interactions that occur...Ch. 18 - Prob. 18.54PCh. 18 - Prob. 18.55PCh. 18 - Which compound has the higher water solubility:...Ch. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - What type of nitrogen heterocycle occurs in both...Ch. 18 - Only one of the N atoms in nicotine has a trigonal...Ch. 18 - Prob. 18.65PCh. 18 - Prob. 18.66PCh. 18 - Why are aqueous solutions of an alkaloid slightly...Ch. 18 - Prob. 18.68PCh. 18 - Prob. 18.69PCh. 18 - Explain why patients with Parkinson’s disease...Ch. 18 - Prob. 18.71PCh. 18 - Prob. 18.72PCh. 18 - Prob. 18.73PCh. 18 - Prob. 18.74PCh. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - Prob. 18.77PCh. 18 - Prob. 18.78PCh. 18 - Prob. 18.79PCh. 18 - Prob. 18.80PCh. 18 - Prob. 18.81PCh. 18 - Prob. 18.82PCh. 18 - Prob. 18.83PCh. 18 - Prob. 18.84PCh. 18 - Prob. 18.85PCh. 18 - Prob. 18.86PCh. 18 - Prob. 18.87PCh. 18 - Why do some antihistamines cause drowsiness while...Ch. 18 - Prob. 18.89PCh. 18 - Prob. 18.90PCh. 18 - Compare the structures of morphine and heroin....Ch. 18 - Prob. 18.92CP
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- Below is the structure of Clemastine and its functional groups. Which of the following statements regarding Clemastine and its functional groups is NOT true? * Ether Tertiary amines CH CH3 Halogenated aromatic hydrocarbon Aromatic hydrocarbon Aliphatic hydrocarbons Clemastine (Tavist) Aromatic hydrocarbon is lipophilic Halogenated aromatic hydrocarbon is lipophilic. Tertiary amine is hydrophobic. Ether is hydrophilic.arrow_forwardN-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomersarrow_forwardGive the IUPAC name for the following acid amide: 0 CH3CH2CH(CH3)CH2CH(CH3)CH2C NH2arrow_forward
- r Talking: Question 14.b of 25 Classify and describe the properties of the following nitrogen containing compound. Provide a systematic name for this structure. 2- N,N- 4- 1- tert- tri di sec- H N H. I N- N,N,N- n- prop but hex Submit +arrow_forwardIf you are given a mixture of three organic compounds (aspirin, β-naphthol, and naphthalene), what procedure would you follow to separate them?arrow_forwardComplete this table for different amine compounds. Chemical propylamine quaternary ammonium ion methylphenylamine Molecular formula C3H9N C₂H7N C5H13N C4H10N Structural formula (CH3)3N (CH3)2NH CH 3 I (CH₂) 11 | H3C(CH2) 11 -N-(CH₂)11CH3 NHCH3 (CH₂)11 CH3 CH3CH2CH2-NH-CH3 + Classification Tertiary Quaternary Tertiary Secondaryarrow_forward
- Because amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardTRUE OR FALSE; The carbonyl carbon in an amide and the carbon in an aromatic ring have the same hybridization.arrow_forward5.) Name the following amines (a. and b.) and draw the structural formula(c.). c.) Cyclopentanamine a.) b.) NH2 NH 2 Нзс— сн — сH 2— сн 3arrow_forward
- Indicate whether the following statement is true or false. Aliphatic amines are more basic than ammonia, whereas aromatic amines are less basic than ammonia.RightFalsearrow_forwardWrite the products of the reaction of diphenhydramine (a base) with the acid HCI shown below. H COCH₂CH₂NCH3 + HC1 CH3 Consider the chemical reaction from the previous question. Are the reactants or products more soluble in water? Briefly explain.arrow_forwardWrite equations showing the basicity and neutralization of amines.arrow_forward
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